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Literature DB >> 23939986

Activation of H2 by a multiply bonded amido-digermyne: evidence for the formation of a hydrido-germylene.

Terrance J Hadlington¹, Markus Hermann, Jiaye Li, Gernot Frenking, Cameron Jones.

Abstract

Entities: Chemical

Keywords: DFT calculations; digermene; digermyne; hydride ligands; hydrogen activation

Year: 2013 PMID： 23939986 DOI： 10.1002/anie.201305689

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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8 in total

1. A stable heavier group 14 analogue of vinylidene.

Authors: Arnab Rit; Jesús Campos; Haoyu Niu; Simon Aldridge
Journal: Nat Chem Date: 2016-08-22 Impact factor: 24.427

2. Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene.

Authors: Zhaowen Dong; Jan Mathis Winkler; Marc Schmidtmann; Thomas Müller
Journal: Chem Sci Date: 2021-03-22 Impact factor: 9.825

3. Diaryltin Dihydrides and Aryltin Trihydrides with Intriguing Stability.

Authors: Beate G Steller; Berenike Doler; Roland C Fischer
Journal: Molecules Date: 2020-02-27 Impact factor: 4.411

4. Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

Authors: Joschua Helmer; Olli J Pakkanen; Chris Gendy; Alexander Hepp; Heikki M Tuononen; Felicitas Lips
Journal: Chem Commun (Camb) Date: 2022-03-10 Impact factor: 6.222

Activation of H2 by a multiply bonded amido-digermyne: evidence for the formation of a hydrido-germylene.

1. A stable heavier group 14 analogue of vinylidene.

2. Three-membered cyclic digermylenes stabilised by an N-heterocyclic carbene.

3. Diaryltin Dihydrides and Aryltin Trihydrides with Intriguing Stability.

4. Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

5. Synthesis of Genuine Germenyl Lithiums and the First Persistent Germenyl Radicals.

6. Molecular Ln(III)-H-E(II) Linkages (Ln=Y, Lu; E=Ge, Sn, Pb).

Review 7. Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis.

Review 8. Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.