Literature DB >> 23939751

Diesel and alkane fuels from biomass by organocatalysis and metal-acid tandem catalysis.

Dajiang Liu1, Eugene Y-X Chen.   

Abstract

Combo deal: Biomass furaldehydes are upgraded into oxygenated diesel and high-quality C10-12 linear alkane fuels. The first of two steps involves solvent-free self-condensation (Umpolung) through organocatalysis using an N-heterocyclic carbene (NHC), yielding C10 -C12 furoin intermediates. In the metal-acid tandem catalysis step, in water, the furoin intermediates are converted into oxygenated biodiesel by hydrogenation, etherification or esterification; or into premium alkane jet fuels by hydrodeoxygenation.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  5-hydroxymethylfurfural; biomass; carbenes; fuels; organocatalysis

Mesh：

Substances：

Year:  2013        PMID： 23939751     DOI： 10.1002/cssc.201300476

Source DB:  PubMed          Journal:  ChemSusChem        ISSN： 1864-5631            Impact factor:   8.928


  4 in total

1.  Electroreductive 5-Hydroxymethylfurfural Dimerization on Carbon Electrodes.

Authors:  Ricarda Kloth; Dmitry V Vasilyev; Karl J J Mayrhofer; Ioannis Katsounaros
Journal:  ChemSusChem       Date:  2021-10-25       Impact factor: 9.140

2.  Organocatalytic upgrading of furfural and 5-hydroxymethyl furfural to C10 and C12 furoins with quantitative yield and atom-efficiency.

Authors:  Hongjun Zang; Eugene Y X Chen
Journal:  Int J Mol Sci       Date:  2015-03-30       Impact factor: 5.923

3.  Synthesis of jet fuel range branched cycloalkanes with mesityl oxide and 2-methylfuran from lignocellulose.

Authors:  Shanshan Li; Ning Li; Wentao Wang; Lin Li; Aiqin Wang; Xiaodong Wang; Tao Zhang
Journal:  Sci Rep       Date:  2016-09-01       Impact factor: 4.379

4.  Enzymatic synthesis of biobased aliphatic-aromatic oligoesters using 5,5'-bis(hydroxymethyl)furoin as a building block.

Authors:  Serena Baraldi; Giancarlo Fantin; Graziano Di Carmine; Daniele Ragno; Arianna Brandolese; Alessandro Massi; Olga Bortolini; Nicola Marchetti; Pier Paolo Giovannini
Journal:  RSC Adv       Date:  2019-09-16       Impact factor: 3.361
  4 in total

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