| Literature DB >> 23934604 |
James A Bellow1, Dong Fang, Natalija Kovacevic, Philip D Martin, Jason Shearer, G Andrés Cisneros, Stanislav Groysman.
Abstract
Caution! Chemists playing: Novel clusters of the form [M2Li2Cl2(OR)4] featuring rare seesaw geometry at the transition metal centers were synthesized for M=Cr-Co. The use of sterically hindering alkoxide ligands, as well as the inclusion of lithium ions in the structures enforces this highly unusual configuration.Entities:
Keywords: alkoxides; cluster compounds; continuous symmetry measures; seesaw geometry; transition metals
Year: 2013 PMID： 23934604 DOI： 10.1002/chem.201302558
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236