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Literature DB >> 23931132

M(12)L(24) spheres with endo and exo coordination sites: scaffolds for non-covalent functionalization.

Kate Harris¹, Qing-Fu Sun, Sota Sato, Makoto Fujita.

Abstract

M12L24 spherical complexes incorporating 24 free pyridine rings on their interior or exterior surfaces were synthesized via the self-assembly of tridentate tris(pyridine) ligands with Pd(2+) ions. Coordination of secondary metal ions in the interior of the spherical framework was achieved through interactions of 24 Ag(+) ions with the free endo pyridine rings.

Entities: Chemical

Year: 2013 PMID： 23931132 DOI： 10.1021/ja4043609

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

6 in total

1. Endo- and Exo-Functionalized Tetraphenylethylene M₁₂L₂₄ Nanospheres: Fluorescence Emission inside a Confined Space.

Authors: Xuzhou Yan; Peifa Wei; Yuhang Liu; Ming Wang; Chuanshuang Chen; Jun Zhao; Guangfeng Li; Manik Lal Saha; Zhixuan Zhou; Zhe An; Xiaopeng Li; Peter J Stang
Journal: J Am Chem Soc Date: 2019-06-07 Impact factor: 15.419

2. Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions.

Authors: Qi-Qiang Wang; Sergio Gonell; Stefan H A M Leenders; Maximilian Dürr; Ivana Ivanović-Burmazović; Joost N H Reek
Journal: Nat Chem Date: 2016-01-11 Impact factor: 24.427

M(12)L(24) spheres with endo and exo coordination sites: scaffolds for non-covalent functionalization.

1. Endo- and Exo-Functionalized Tetraphenylethylene M₁₂L₂₄ Nanospheres: Fluorescence Emission inside a Confined Space.

2. Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions.

3. Automated Rational Design of Metal-Organic Polyhedra.

4. Timing matters: pre-assembly versus post-assembly functionalization of a polyoxovanadate-organic cuboid.

5. How to Control the Rate of Heterogeneous Electron Transfer across the Rim of M₆L₁₂ and M₁₂L₂₄ Nanospheres.

6. Peptide cyclisation promoted by supramolecular complex formation.

M(12)L(24) spheres with endo and exo coordination sites: scaffolds for non-covalent functionalization.

1. Endo- and Exo-Functionalized Tetraphenylethylene M12L24 Nanospheres: Fluorescence Emission inside a Confined Space.

2. Self-assembled nanospheres with multiple endohedral binding sites pre-organize catalysts and substrates for highly efficient reactions.

3. Automated Rational Design of Metal-Organic Polyhedra.

4. Timing matters: pre-assembly versus post-assembly functionalization of a polyoxovanadate-organic cuboid.

5. How to Control the Rate of Heterogeneous Electron Transfer across the Rim of M6L12 and M12L24 Nanospheres.

6. Peptide cyclisation promoted by supramolecular complex formation.

1. Endo- and Exo-Functionalized Tetraphenylethylene M₁₂L₂₄ Nanospheres: Fluorescence Emission inside a Confined Space.

5. How to Control the Rate of Heterogeneous Electron Transfer across the Rim of M₆L₁₂ and M₁₂L₂₄ Nanospheres.