| Literature DB >> 23928823 |
Kazuya Nushiro1, Satoshi Kikuchi, Tohru Yamada.
Abstract
Catalytic enantioselective Claisen rearrangement was drastically enhanced under microwave irradiation conditions without any loss of the enantioselectivity. Based on Arrhenius plots it was revealed that enantioselectivity decreased as the internal reaction temperature increased. Therefore, this reaction acceleration would NOT be caused by only a simple thermal effect.Year: 2013 PMID: 23928823 DOI: 10.1039/c3cc44610g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222