Literature DB >> 23927785

Phenanthridine synthesis through iron-catalyzed intramolecular N-arylation of O-acetyl oxime.

Indubhusan Deb1, Naohiko Yoshikai.   

Abstract

O-Acetyl oximes derived from 2'-arylacetophenones undergo N-O bond cleavage/intramolecular N-arylation in the presence of a catalytic amount of iron(III) acetylacetonate in acetic acid. In combination with the conventional cross-coupling or directed C-H arylation, the reaction offers a convenient route to substituted phenanthridines.

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Year:  2013        PMID: 23927785     DOI: 10.1021/ol4020392

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  3 in total

1.  Catalytic Oxidative Cyclization of 2'-Arylbenzaldehyde Oxime Ethers under Photoinduced Electron Transfer Conditions.

Authors:  Julie L Hofstra; Brittany R Grassbaugh; Quan M Tran; Nicholas R Armada; H J Peter de Lijser
Journal:  J Org Chem       Date:  2014-12-09       Impact factor: 4.354

2.  Expanding the palette of phenanthridinium cations.

Authors:  Andrew G Cairns; Hans Martin Senn; Michael P Murphy; Richard C Hartley
Journal:  Chemistry       Date:  2014-03-24       Impact factor: 5.236

Review 3.  Come-back of phenanthridine and phenanthridinium derivatives in the 21st century.

Authors:  Lidija-Marija Tumir; Marijana Radić Stojković; Ivo Piantanida
Journal:  Beilstein J Org Chem       Date:  2014-12-10       Impact factor: 2.883

  3 in total

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