| Literature DB >> 23927556 |
Álvaro Gutiérrez-Bonet1, Areli Flores-Gaspar, Ruben Martin.
Abstract
An Fe-catalyzed conversion of aldehydes to ketones via [1,2]-shift has been developed. This skeletal rearrangement shows a wide substrate scope and chemoselectivity profile while exhibiting an excellent [1,2]-aryl or [1,2]-alkyl shift selectivity that is easily switched by electronic effects.Entities:
Year: 2013 PMID： 23927556 DOI： 10.1021/ja4068707
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419