Literature DB >> 23925541

Phosphaalkene vs. phosphinidene: the nature of the P-C bond in carbonyl-decorated carbene → PPh adducts.

Roberta R Rodrigues1, Christopher L Dorsey, Chelsee A Arceneaux, Todd W Hudnall.   

Abstract

Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses.

Entities:  

Year:  2014        PMID： 23925541     DOI： 10.1039/c3cc45134h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  A Carbene-Stabilized Boryl-Phosphinidene.

Authors:  Samir Kumar Sarkar; Subrata Kundu; Mohd Nazish; Johannes Kretsch; Regine Herbst-Irmer; Dietmar Stalke; Parameswaran Parvathy; Pattiyil Parameswaran; Herbert W Roesky
Journal:  Chemistry       Date:  2022-04-13       Impact factor: 5.020

2.  Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.

Authors:  Kuntal Pal; Oliver B Hemming; Benjamin M Day; Thomas Pugh; David J Evans; Richard A Layfield
Journal:  Angew Chem Int Ed Engl       Date:  2015-12-08       Impact factor: 15.336

3.  Isolation of cationic and neutral (allenylidene)(carbene) and bis(allenylidene)gold complexes.

Authors:  Liqun Jin; Mohand Melaimi; Arseni Kostenko; Miriam Karni; Yitzhak Apeloig; Curtis E Moore; Arnold L Rheingold; Guy Bertrand
Journal:  Chem Sci       Date:  2015-11-16       Impact factor: 9.825

4.  Stretching the P-C Bond. Variations on Carbenes and Phosphanes.

Authors:  Dániel Buzsáki; Zsolt Kelemen; László Nyulászi
Journal:  J Phys Chem A       Date:  2020-03-24       Impact factor: 2.781
  4 in total

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