Literature DB >> 23925040

Vanadium-catalyzed deoxydehydration of glycols.

Garry Chapman1, Kenneth M Nicholas.   

Abstract

A survey of several metavandate (VO3(-)) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(V)dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenylphosphine or sodium sulfite as reductants.

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Year:  2013        PMID: 23925040     DOI: 10.1039/c3cc44656e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Direct Deoxydehydration of Cyclic trans-Diol Substrates: An Experimental and Computational Study of the Reaction Mechanism of Vanadium(V)-based Catalysis*.

Authors:  Ebru Aksanoglu; Yee Hwee Lim; Richard A Bryce
Journal:  ChemSusChem       Date:  2021-02-09       Impact factor: 8.928

2.  First Evidence of the Double-Bond Formation by Deoxydehydration of Glycerol and 1,2-Propanediol in Ionic Liquids.

Authors:  Andrea Mascitti; Giuseppe Scioli; Lucia Tonucci; Valentino Canale; Raimondo Germani; Pietro Di Profio; Nicola d'Alessandro
Journal:  ACS Omega       Date:  2022-08-01
  2 in total

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