| Literature DB >> 23924355 |
Raphaël F Guignard1, Laurent Petit, Samir Z Zard.
Abstract
A simple sequence for the net contra-thermodynamic isomerization of cyclic trisubstituted alkenes is reported consisting of a radical addition of p-chlorothiophenol, followed by oxidation to the sulfoxide and thermal syn-elimination to give the least substituted isomeric cycloalkene.Entities:
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Year: 2013 PMID： 23924355 DOI： 10.1021/ol4018744
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005