Literature DB >> 23917404

Hydrogen-bond mediated regio- and enantioselectivity in a C-H amination reaction catalysed by a supramolecular Rh(II) complex.

Thorsten Höke1, Eberhardt Herdtweck, Thorsten Bach.   

Abstract

Enantioselective (up to 74% ee) and regioselective C-H amination reactions of 3-benzylquinolones were achieved with a chiral C2-symmetric Rh(II) complex exhibiting two lactam binding sites for substrate coordination via hydrogen bonds.

Entities:  

Year:  2013        PMID： 23917404     DOI： 10.1039/c3cc44197k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  6 in total

1.  Enantioselective Intermolecular Radical C-H Amination.

Authors:  Li-Mei Jin; Pan Xu; Jingjing Xie; X Peter Zhang
Journal:  J Am Chem Soc       Date:  2020-11-25       Impact factor: 15.419

Review 2.  Transition Metal Catalysis Controlled by Hydrogen Bonding in the Second Coordination Sphere.

Authors:  Joost N H Reek; Bas de Bruin; Sonja Pullen; Tiddo J Mooibroek; Alexander M Kluwer; Xavier Caumes
Journal:  Chem Rev       Date:  2022-05-20       Impact factor: 72.087

3.  Harnessing non-covalent interactions to exert control over regioselectivity and site-selectivity in catalytic reactions.

Authors:  Holly J Davis; Robert J Phipps
Journal:  Chem Sci       Date:  2016-10-05       Impact factor: 9.825

4.  Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(ii) catalysts.

Authors:  Jan-Philipp Berndt; Yevhenii Radchenko; Jonathan Becker; Christian Logemann; Dhaka R Bhandari; Radim Hrdina; Peter R Schreiner
Journal:  Chem Sci       Date:  2019-02-06       Impact factor: 9.825

5.  Enantioselective Intermolecular C-H Amination Directed by a Chiral Cation.

Authors:  Alexander Fanourakis; Benjamin D Williams; Kieran J Paterson; Robert J Phipps
Journal:  J Am Chem Soc       Date:  2021-06-28       Impact factor: 15.419

6.  A domino reaction for generating β-aryl aldehydes from alkynes by substrate recognition catalysis.

Authors:  Weiwei Fang; Felix Bauer; Yaxi Dong; Bernhard Breit
Journal:  Nat Commun       Date:  2019-10-25       Impact factor: 14.919
  6 in total

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