Literature DB >> 23913436

The 2-phosphaethynolate anion: a convenient synthesis and [2+2] cycloaddition chemistry.

Andrew R Jupp1, Jose M Goicoechea.   

Abstract

Hip to be square: Direct carbonylation of solutions of the heptaphosphide trianion (P7(3-)) afforded the phosphaethynolate anion in moderate yields. This species undergoes [2+2] cycloaddition reactions with diphenylketene and bis(2,6-diisopropylphenyl)carbodiimide to yield the anionic four-membered heterocycles P[C(O)]2C(C6H5)2(-) and PC(O)(CNDipp)NDipp(-) .
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  cycloaddition; organophosphorus chemistry; phosphaethynolate anion; phosphorus; polyphosphides

Year:  2013        PMID： 23913436     DOI： 10.1002/anie.201305235

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  19 in total

1.  Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP].

Authors:  Jacob E Walley; Levi S Warring; Erik Kertész; Guocang Wang; Diane A Dickie; Zoltán Benkő; Robert J Gilliard
Journal:  Inorg Chem       Date:  2021-03-09       Impact factor: 5.165

2.  Phosphide delivery to a cyclotrisilene.

Authors:  Thomas P Robinson; Michael J Cowley; David Scheschkewitz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2014-11-21       Impact factor: 15.336

3.  Exploiting the Brønsted acidity of phosphinecarboxamides for the synthesis of new phosphides and phosphines.

Authors:  Andrew R Jupp; Gemma Trott; Éléonore Payen de la Garanderie; James D G Holl; Duncan Carmichael; Jose M Goicoechea
Journal:  Chemistry       Date:  2015-04-17       Impact factor: 5.236

4.  Synthesis of anionic phosphorus-containing heterocycles by intramolecular cyclizations involving N-functionalized phosphinecarboxamides.

Authors:  Thomas P Robinson; Jose M Goicoechea
Journal:  Chemistry       Date:  2015-03-03       Impact factor: 5.236

5.  (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles.

Authors:  Max M Hansmann; David A Ruiz; Liu Leo Liu; Rodolphe Jazzar; Guy Bertrand
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

6.  Cyclo-oligomerization of isocyanates with Na(PH2) or Na(OCP) as "P-" anion sources.

Authors:  Dominikus Heift; Zoltán Benkő; Hansjörg Grützmacher; Andrew R Jupp; Jose M Goicoechea
Journal:  Chem Sci       Date:  2015-05-13       Impact factor: 9.825

7.  HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.

Authors:  Alexander Hinz; René Labbow; Chris Rennick; Axel Schulz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2017-03-02       Impact factor: 15.336

8.  Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene.

Authors:  Daniel W N Wilson; Mauricio P Franco; William K Myers; John E McGrady; Jose M Goicoechea
Journal:  Chem Sci       Date:  2019-12-02       Impact factor: 9.825

9.  Ambient-Temperature Synthesis of 2-Phosphathioethynolate, PCS-, and the Ligand Properties of ECX- (E = N, P; X = O, S).

Authors:  Andrew R Jupp; Michael B Geeson; John E McGrady; Jose M Goicoechea
Journal:  Eur J Inorg Chem       Date:  2015-11-04       Impact factor: 2.524

10.  The 2-Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes.

Authors:  Alexander Hinz; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-20       Impact factor: 15.336
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