| Literature DB >> 23907931 |
Christian Marquardt1, Ariane Adolf, Andreas Stauber, Michael Bodensteiner, Alexander V Virovets, Alexey Y Timoshkin, Manfred Scheer.
Abstract
Exclusively hydrogen-substituted arsanylboranes: The synthesis of the unprecedented Lewis base stabilized monomeric parent compound of the arsanylborane H2AsBH2⋅NMe3 was achieved in a one-pot reaction in high yield and purity. The analogous phosphanylborane was synthesized in a similar manner. A series of different reactions was performed on H2AsBH2⋅NMe3 to show its broad reactivity pattern.Entities:
Keywords: Group 13/15 compounds; Lewis acid base adducts; arsenic; boron; phosphorus; primary arsine
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Year: 2013 PMID： 23907931 DOI： 10.1002/chem.201302110
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236