Literature DB >> 23900667

Facile synthesis of heterotrimetallic metal-string complex [NiCoRh(dpa)4Cl2] through direct metal replacement.

Ming-Chuan Cheng1, Chi-Lun Mai, Chen-Yu Yeh, Gene-Hsiang Lee, Shie-Ming Peng.   

Abstract

This communication provides a practical strategy for the synthesis of heterotrimetallic extended metal atom chains with supported dpa(-) ligands. The transformation of the CoCoRh to a NiCoRh trinuclear complex can be achieved by direct metallic replacement. Furthermore, the first (CoRh)(4+) metal-metal bond is described here.

Entities:  

Year:  2013        PMID: 23900667     DOI: 10.1039/c3cc43909g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Improving the Solubility of Hexanuclear Heterometallic Extended Metal Atom Chain Compounds in Nonpolar Solvents by Introducing Alkyl Amine Moieties.

Authors:  Kazuhiro Uemura; Erina Yasuda; Yuko Sugiyama
Journal:  ACS Omega       Date:  2021-07-07
  1 in total

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