Literature DB >> 23900613

Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides.

Lu Wang1, Chao Liu, Ruopeng Bai, Yani Pan, Aiwen Lei.   

Abstract

The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an intramolecular hydrogen transfer process.

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Year:  2013        PMID: 23900613     DOI: 10.1039/c3cc43875a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Gas-phase intramolecular cyclization of argentinated N-allylbenzamides.

Authors:  Hezhi Sun; Yunfeng Chai; Zhe Jin; Cuirong Sun; Yuanjiang Pan
Journal:  J Am Soc Mass Spectrom       Date:  2015-02-24       Impact factor: 3.109

2.  A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C-C Coupling in Air.

Authors:  Gourab Kundu; Theresa Sperger; Kari Rissanen; Franziska Schoenebeck
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-28       Impact factor: 15.336

3.  Direct Synthesis of Enamides via Electrophilic Activation of Amides.

Authors:  Philipp Spieß; Martin Berger; Daniel Kaiser; Nuno Maulide
Journal:  J Am Chem Soc       Date:  2021-07-07       Impact factor: 15.419

  3 in total

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