Literature DB >> 23900201

A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [Al(III)4(H2O)10(β-XW9O33H)2](6-) (X = As(III), Sb(III)).

Mauro Carraro1, Bassem S Bassil, Antonio Sorarù, Serena Berardi, Andreas Suchopar, Ulrich Kortz, Marcella Bonchio.   

Abstract

The Al(III)-containing polyanions [Al(III)4(H2O)10(β-XW9O33H)2](4-) with X = As(III) (1) and Sb(III) (2) feature four aluminum(III) centers sandwiched by two trivacant (β-XW9O33) Keggin units, and trigger peroxide catalysis as well as substrate coordination via multiple Lewis acid site interactions.

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Year:  2013        PMID： 23900201     DOI： 10.1039/c3cc44077j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Trisubstituted 4f- and 4d tungstoantimonates as artificial phosphoesterases for nerve agent degradation.

Authors:  Elias Tanuhadi; Annette Rompel
Journal:  Chem Commun (Camb)       Date:  2022-07-12       Impact factor: 6.065

2.  Aluminum-Substituted Keggin Germanotungstate [HAl(H2O)GeW11O39]4-: Synthesis, Characterization, and Antibacterial Activity.

Authors:  Elias Tanuhadi; Nadiia I Gumerova; Alexander Prado-Roller; Mathea Sophia Galanski; Hana Čipčić-Paljetak; Donatella Verbanac; Annette Rompel
Journal:  Inorg Chem       Date:  2020-12-17       Impact factor: 5.165

3.  A H2O2/HBr system - several directions but one choice: oxidation-bromination of secondary alcohols into mono- or dibromo ketones.

Authors:  Gennady I Nikishin; Nadezhda I Kapustina; Liubov L Sokova; Oleg V Bityukov; Alexander O Terent'ev
Journal:  RSC Adv       Date:  2018-08-10       Impact factor: 4.036
  3 in total

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