Literature DB >> 23895674

Chemoenzymatic total synthesis of the phytotoxic geranylcyclohexentriol (-)-phomentrioloxin.

Xinghua Ma1, Martin G Banwell, Anthony C Willis.   

Abstract

The enantiomeric form, 1R, of the structure (1S) assigned to the phytotoxic natural product phomentrioloxin has been synthesized in seven steps from the homochiral cis-1,2-dihydrocatechol 3. These studies reveal that the true structure of phomentrioloxin is represented by 1R and not by 1S.

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Year:  2013        PMID: 23895674     DOI: 10.1021/np4002866

Source DB:  PubMed          Journal:  J Nat Prod        ISSN: 0163-3864            Impact factor:   4.050


  2 in total

1.  Dearomative dihydroxylation with arenophiles.

Authors:  Emma H Southgate; Jola Pospech; Junkai Fu; Daniel R Holycross; David Sarlah
Journal:  Nat Chem       Date:  2016-08-22       Impact factor: 24.427

Review 2.  Benefits of Unconventional Methods in the Total Synthesis of Natural Products.

Authors:  Tomas Hudlicky
Journal:  ACS Omega       Date:  2018-12-14
  2 in total

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