Literature DB >> 23884450

Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides.

Yoshihiro Miyake1, Shin-ichi Ota, Masashi Shibata, Kazunari Nakajima, Yoshiaki Nishibayashi.   

Abstract

Reactions of propargylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) have been found to give the corresponding trifluoromethylated products in good to high yields with a high selectivity.

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Year:  2013        PMID： 23884450     DOI： 10.1039/c3cc44434a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Metal-catalyzed Decarboxylative Fluoroalkylation Reactions.

Authors:  Brett R Ambler; Ming-Hsiu Yang; Ryan A Altman
Journal:  Synlett       Date:  2016-12       Impact factor: 2.454

2.  Nickel-Catalyzed Alkyl-Alkyl Cross-Couplings of Fluorinated Secondary Electrophiles: A General Approach to the Synthesis of Compounds having a Perfluoroalkyl Substituent.

Authors:  Yufan Liang; Gregory C Fu
Journal:  Angew Chem Int Ed Engl       Date:  2015-06-12       Impact factor: 15.336

3.  Copper-Catalyzed Decarboxylative Trifluoromethylation of Propargyl Bromodifluoroacetates.

Authors:  Brett R Ambler; Santosh Peddi; Ryan A Altman
Journal:  Synthesis (Stuttg)       Date:  2014-07-15       Impact factor: 3.157

4.  Ligand-Controlled Regioselective Copper-Catalyzed Trifluoromethylation To Generate (Trifluoromethyl)allenes.

Authors:  Brett R Ambler; Santosh Peddi; Ryan A Altman
Journal:  Org Lett       Date:  2015-04-24       Impact factor: 6.005

Review 5.  Progress in copper-catalyzed trifluoromethylation.

Authors:  Guan-Bao Li; Chao Zhang; Chun Song; Yu-Dao Ma
Journal:  Beilstein J Org Chem       Date:  2018-01-17       Impact factor: 2.883

6.  Cu-Mediated trifluoromethylation of benzyl, allyl and propargyl methanesulfonates with TMSCF3.

Authors:  Xueliang Jiang; Feng-Ling Qing
Journal:  Beilstein J Org Chem       Date:  2013-12-12       Impact factor: 2.883

7.  Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols.

Authors:  Daniels Posevins; Aitor Bermejo-López; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2021-09-02       Impact factor: 16.823
  7 in total

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