| Literature DB >> 23881819 |
Marina Frank1, Jakob Hey, Ilker Balcioglu, Yu-Sheng Chen, Dietmar Stalke, Tomoyoshi Suenobu, Shunichi Fukuzumi, Holm Frauendorf, Guido H Clever.
Abstract
A breath of fresh air is sufficient for the eightfold S-monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square-planar-coordinated Pd(II) cations. Besides these two cages, which were both characterized by X-ray crystallography, an eightfold S-dioxygenated double-cage was obtained under harsher oxidation conditions.Entities:
Keywords: cage compounds; interpenetration; phenothiazines; redox chemistry; supramolecular chemistry
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Year: 2013 PMID: 23881819 DOI: 10.1002/anie.201302536
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336