Literature DB >> 23875702

Iron(II)-catalyzed asymmetric intramolecular aminohydroxylation of indoles.

Yong-Qiang Zhang1, Yong-An Yuan, Guan-Sai Liu, Hao Xu.   

Abstract

An enantioselective intramolecular indole aminohydroxylation reaction is catalyzed by iron(II)-chiral bisoxazoline (BOX) complexes (ee up to 99%, dr > 20:1). This discovery enables expedient asymmetric synthesis of a series of biologically active 3-amino oxindoles and 3-amino indolanes.

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Year:  2013        PMID： 23875702     DOI： 10.1021/ol401666e

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  10 in total

1.  Directed, Palladium(II)-Catalyzed Intermolecular Aminohydroxylation of Alkenes Using a Mild Oxidation System.

Authors:  Tian Zeng; Zhen Liu; Michael A Schmidt; Martin D Eastgate; Keary M Engle
Journal:  Org Lett       Date:  2018-06-11       Impact factor: 6.005

2.  Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis.

Authors:  Robert Connon; Brendan Roche; Balaji V Rokade; Patrick J Guiry
Journal:  Chem Rev       Date:  2021-05-21       Impact factor: 60.622

3.  Practical Synthetic Procedures for the Iron-Catalyzed Intermolecular Olefin Aminohydroxylation Using Functionalized Hydroxylamines.

Authors:  Cheng-Liang Zhu; Deng-Fu Lu; Jeffrey D Sears; Zhen-Xin Jia; Hao Xu
Journal:  Synthesis (Stuttg)       Date:  2016-07-25       Impact factor: 3.157

4.  Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes.

Authors:  Honghui Lei; John H Conway; Caleb C Cook; Tomislav Rovis
Journal:  J Am Chem Soc       Date:  2019-07-16       Impact factor: 15.419

5.  Nitrene-mediated intermolecular N-N coupling for efficient synthesis of hydrazides.

Authors:  Hao Wang; Hoimin Jung; Fangfang Song; Shiyang Zhu; Ziqian Bai; Danye Chen; Gang He; Sukbok Chang; Gong Chen
Journal:  Nat Chem       Date:  2021-03-22       Impact factor: 24.427

6.  Iron-Catalyzed Direct Diazidation for a Broad Range of Olefins.

Authors:  Yong-An Yuan; Deng-Fu Lu; Yun-Rong Chen; Hao Xu
Journal:  Angew Chem Int Ed Engl       Date:  2015-11-23       Impact factor: 15.336

7.  Iron-Catalyzed Diastereoselective Intramolecular Olefin Aminobromination with Bromide Ion.

Authors:  Jun-Shan Tian; Cheng-Liang Zhu; Yun-Rong Chen; Hao Xu
Journal:  Synthesis (Stuttg)       Date:  2015-06       Impact factor: 3.157

8.  Copper-catalyzed aminooxygenation of styrenes with N-fluorobenzenesulfonimide and N-hydroxyphthalimide derivatives.

Authors:  Yan Li; Xue Zhou; Guangfan Zheng; Qian Zhang
Journal:  Beilstein J Org Chem       Date:  2015-12-24       Impact factor: 2.883

9.  Iron(II)-catalyzed intermolecular amino-oxygenation of olefins through the N-O bond cleavage of functionalized hydroxylamines.

Authors:  Deng-Fu Lu; Cheng-Liang Zhu; Zhen-Xin Jia; Hao Xu
Journal:  J Am Chem Soc       Date:  2014-09-16       Impact factor: 15.419

10.  Iron(II)-catalyzed asymmetric intramolecular olefin aminochlorination using chloride ion.

Authors:  Cheng-Liang Zhu; Jun-Shan Tian; Zhen-Yuan Gu; Guo-Wen Xing; Hao Xu
Journal:  Chem Sci       Date:  2015-03-13       Impact factor: 9.825
  10 in total

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