Literature DB >> 23873845

Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex.

Sander Oldenhof1, Bas de Bruin, Martin Lutz, Maxime A Siegler, Frederic W Patureau, Jarl Ivar van der Vlugt, Joost N H Reek.   

Abstract

Erase the base: An iridium complex based on a cooperative ligand that functions as an internal base is reported. This complex can rapidly and cleanly dehydrogenate formic acid in absence of external base, a reaction that is required if formic acid is to be exploited as an energy carrier (see scheme).
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  H2 production; bifunctional activation; cooperative effects; dehydrogenation; iridium

Mesh：

Substances：

Year:  2013        PMID： 23873845     DOI： 10.1002/chem.201302230

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  8 in total

1.  Iridium-based hydride transfer catalysts: from hydrogen storage to fine chemicals.

Authors:  Zhiyao Lu; Valeriy Cherepakhin; Ivan Demianets; Paul J Lauridsen; Travis J Williams
Journal:  Chem Commun (Camb)       Date:  2018-07-10       Impact factor: 6.222

2.  Structural analysis of transient reaction intermediate in formic acid dehydrogenation catalysis using two-dimensional IR spectroscopy.

Authors:  Yufan Zhang; Xin Chen; Bin Zheng; Xunmin Guo; Yupeng Pan; Hailong Chen; Huaifeng Li; Shixiong Min; Chao Guan; Kuo-Wei Huang; Junrong Zheng
Journal:  Proc Natl Acad Sci U S A       Date:  2018-11-19       Impact factor: 11.205

3.  A DFT Study of CO2 Hydrogenation on Faujasite-Supported Ir4 Clusters: on the Role of Water for Selectivity Control.

Authors:  Bartłomiej M Szyja; Daniel Smykowski; Jerzy Szczygieł; Emiel J M Hensen; Evgeny A Pidko
Journal:  ChemCatChem       Date:  2016-06-23       Impact factor: 5.686

4.  Reactivity of a Ruthenium-Carbonyl Complex in the Methanol Dehydrogenation Reaction.

Authors:  Fenna F van de Watering; Martin Lutz; Wojciech I Dzik; Bas de Bruin; Joost N H Reek
Journal:  ChemCatChem       Date:  2016-08-18       Impact factor: 5.686

5.  Development of an Iridium-Based Catalyst for High-Pressure Evolution of Hydrogen from Formic Acid.

Authors:  Masayuki Iguchi; Yuichiro Himeda; Yuichi Manaka; Hajime Kawanami
Journal:  ChemSusChem       Date:  2016-08-17       Impact factor: 8.928

6.  Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions.

Authors:  Sandra Y de Boer; Ties J Korstanje; Stefan R La Rooij; Rogier Kox; Joost N H Reek; Jarl Ivar van der Vlugt
Journal:  Organometallics       Date:  2017-04-06       Impact factor: 3.876

7.  Dehydrogenation of formic acid by Ir-bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand.

Authors:  Sander Oldenhof; Martin Lutz; Bas de Bruin; Jarl Ivar van der Vlugt; Joost N H Reek
Journal:  Chem Sci       Date:  2014-10-22       Impact factor: 9.825

8.  A prolific catalyst for dehydrogenation of neat formic acid.

Authors:  Jeff Joseph A Celaje; Zhiyao Lu; Elyse A Kedzie; Nicholas J Terrile; Jonathan N Lo; Travis J Williams
Journal:  Nat Commun       Date:  2016-04-14       Impact factor: 14.919
  8 in total

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