| Literature DB >> 23873334 |
Miguel A Esteruelas1, Ana M López, Malka Mora, Enrique Oñate.
Abstract
Heterolytic B-H activation and H-H formation on an Os-SH bond give borylthiolate-dihydrogen derivatives. These species exchange borylthiol by borane to afford σ-borane derivatives or release H2 and undergo a hydride-boryl exchange to yield boryl-hydrogensulfide complexes depending on the boryl group bonded to the sulfur atom.Entities:
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Year: 2013 PMID： 23873334 DOI： 10.1039/c3cc44102d
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222