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Literature DB >> 23865433

Dinitrogen reduction by a chromium(0) complex supported by a 16-membered phosphorus macrocycle.

Michael T Mock¹, Shentan Chen, Molly O'Hagan, Roger Rousseau, William G Dougherty, W Scott Kassel, R Morris Bullock.

Abstract

We report a rare example of a Cr-N2 complex supported by a 16-membered phosphorus macrocycle containing pendant amine bases. Reactivity with acid afforded hydrazinium and ammonium, representing the first example of N2 reduction by a Cr-N2 complex. Computational analysis examined the thermodynamically favored protonation steps of N2 reduction with Cr leading to the formation of hydrazine.

Entities: Chemical

Year: 2013 PMID： 23865433 DOI： 10.1021/ja405668u

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

7 in total

1. Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization.

Authors: John J Kiernicki; Matthias Zeller; Nathaniel K Szymczak
Journal: Inorg Chem Date: 2020-06-18 Impact factor: 5.165

7. Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.

Authors: Shogo Kuriyama; Kazuya Arashiba; Kazunari Nakajima; Hiromasa Tanaka; Kazunari Yoshizawa; Yoshiaki Nishibayashi
Journal: Chem Sci Date: 2015-04-20 Impact factor: 9.825

7 in total

Dinitrogen reduction by a chromium(0) complex supported by a 16-membered phosphorus macrocycle.

1. Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization.

2. Hydrogen Bonding to a Dinitrogen Complex at Room Temperature: Impacts on N₂ Activation.

3. Isocyanide and Phosphine Oxide Coordination in Binuclear Chromium Pacman Complexes.

4. Exploring secondary-sphere interactions in Fe-N _x H _y complexes relevant to N₂ fixation.

5. Synthesis and Structure of Iron (II) Complexes of Functionalized 1,5-Diaza-3,7-Diphosphacyclooctanes.

6. Ligand-enabled and magnesium-activated hydrogenation with earth-abundant cobalt catalysts.

7. Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum-dinitrogen complexes: unique behavior of ferrocene moiety as redox active site.