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Literature DB >> 23832007

Reversible carbon-carbon bond formation between carbonyl compounds and a ruthenium pincer complex.

Chelsea A Huff¹, Jeff W Kampf, Melanie S Sanford.

Abstract

This communication describes the reversible reaction of a ruthenium pincer complex with a variety of carbonyl compounds. Both NMR spectroscopic and X-ray crystallographic characterization of isomeric carbonyl adducts are reported, and the equilibrium constants for carbonyl binding have been determined.

Entities: Chemical

Year: 2013 PMID： 23832007 DOI： 10.1039/c3cc43517b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

5 in total

1. Facile synthesis of amides via acceptorless dehydrogenative coupling of aryl epoxides and amines.

Authors: Yaoyu Liang; Jie Luo; David Milstein
Journal: Chem Sci Date: 2022-04-26 Impact factor: 9.969

2. Metal-Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C-C Bond Formation and Rate Control in Catalysis.

Authors: Fabian Ebner; Lukas Maximilian Sigmund; Lutz Greb
Journal: Angew Chem Int Ed Engl Date: 2020-08-18 Impact factor: 15.336

Reversible carbon-carbon bond formation between carbonyl compounds and a ruthenium pincer complex.

1. Facile synthesis of amides via acceptorless dehydrogenative coupling of aryl epoxides and amines.

2. Metal-Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C-C Bond Formation and Rate Control in Catalysis.

3. Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia.

4. Oxidation of Organic Compounds Using Water as the Oxidant with H₂ Liberation Catalyzed by Molecular Metal Complexes.

5. Hydration of nitriles using a metal-ligand cooperative ruthenium pincer catalyst.

Reversible carbon-carbon bond formation between carbonyl compounds and a ruthenium pincer complex.

1. Facile synthesis of amides via acceptorless dehydrogenative coupling of aryl epoxides and amines.

2. Metal-Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C-C Bond Formation and Rate Control in Catalysis.

3. Acceptorless dehydrogenative synthesis of primary amides from alcohols and ammonia.

4. Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes.

5. Hydration of nitriles using a metal-ligand cooperative ruthenium pincer catalyst.

4. Oxidation of Organic Compounds Using Water as the Oxidant with H₂ Liberation Catalyzed by Molecular Metal Complexes.