| Literature DB >> 23829317 |
Xi-Yan Dong1, Bo Li, Bin-Bin Ma, Shi-Jun Li, Ming-Ming Dong, Yan-Yan Zhu, Shuang-Quan Zang, You Song, Hong-Wei Hou, Thomas C W Mak.
Abstract
A polar homochiral 3D MOF [{Co2(L)(bpe)(H2O)}·5H2O]n constructed with cobalt(II) and a new ligand N-(1,3-dicarboxy-5-benzyl)-carboxymethylglycine (H4L) accommodates ordered helical water streams in its helical grooves. It provides the first example of switchable ferroelectric and optical behavior through two-step reversible single-crystal to single-crystal transformation (SCSC) upon desorption/adsorption of water spirals and coordinated water molecules, respectively.Entities:
Mesh：
Substances：
Year: 2013 PMID： 23829317 DOI： 10.1021/ja403449k
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419