| Literature DB >> 23828402 |
Ivana Fleischer1, Lipeng Wu, Irina Profir, Ralf Jackstell, Robert Franke, Matthias Beller.
Abstract
The ruthenium-catalyzed hydroformylation of 1- and 2-octene to give preferentially the corresponding linear aldehyde is reported. The catalyst system comprising of Ru3 (CO)12 and an imidazole-substituted monophosphine ligand allows for high chemo- and regioselectivity. The hydroformylation proceeds with unprecedented rates for a ruthenium-based catalyst.Entities:
Keywords: aldehydes; carbonylation; hydroformylation; phosphine; ruthenium
Year: 2013 PMID： 23828402 DOI： 10.1002/chem.201300899
Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236