Literature DB >> 23813875

A dense metal-organic framework for enhanced magnetic refrigeration.

Giulia Lorusso1, Joseph W Sharples, Elias Palacios, Olivier Roubeau, Euan K Brechin, Roberta Sessoli, Andrea Rossin, Floriana Tuna, Eric J L McInnes, David Collison, Marco Evangelisti.   

Abstract

The three-dimensional metal-organic framework Gd(HCOO)3 is characterized by a relatively compact crystal lattice of weakly interacting Gd(3+) spin centers interconnected via lightweight formate ligands, overall providing a remarkably large magnetic:non-magnetic elemental weight ratio. The resulting magnetocaloric effect per unit volume is decidedly superior in Gd(HCOO)3 than in the best known magnetic refrigerant materials for liquid-helium temperatures and low-moderate applied fields.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  gadolinium formate; magnetic refrigeration; magnetocaloric effect; metal-organic frameworks; molecule-based magnets

Year:  2013        PMID： 23813875     DOI： 10.1002/adma.201301997

Source DB:  PubMed          Journal:  Adv Mater        ISSN： 0935-9648            Impact factor:   30.849


  12 in total

1.  Free-Spin Dominated Magnetocaloric Effect in Dense Gd3+ Double Perovskites.

Authors:  EliseAnne C Koskelo; Cheng Liu; Paromita Mukherjee; Nicola D Kelly; Siân E Dutton
Journal:  Chem Mater       Date:  2022-03-29       Impact factor: 9.811

2.  Quantum signatures of a molecular nanomagnet in direct magnetocaloric measurements.

Authors:  Joseph W Sharples; David Collison; Eric J L McInnes; Jürgen Schnack; Elias Palacios; Marco Evangelisti
Journal:  Nat Commun       Date:  2014-10-22       Impact factor: 14.919

3.  Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework.

Authors:  Ying Tian; Alessandro Stroppa; Yisheng Chai; Liqin Yan; Shouguo Wang; Paolo Barone; Silvia Picozzi; Young Sun
Journal:  Sci Rep       Date:  2014-08-14       Impact factor: 4.379

4.  Giant direct and inverse magnetocaloric effect linked to the same forward martensitic transformation.

Authors:  J I Pérez-Landazábal; V Recarte; V Sánchez-Alarcos; J J Beato-López; J A Rodríguez-Velamazán; J Sánchez-Marcos; C Gómez-Polo; E Cesari
Journal:  Sci Rep       Date:  2017-10-17       Impact factor: 4.379

5.  Imposing high-symmetry and tuneable geometry on lanthanide centres with chelating Pt and Pd metalloligands.

Authors:  Mikkel A Sørensen; Høgni Weihe; Morten G Vinum; Jesper S Mortensen; Linda H Doerrer; Jesper Bendix
Journal:  Chem Sci       Date:  2017-02-28       Impact factor: 9.825

6.  Observation of the influence of dipolar and spin frustration effects on the magnetocaloric properties of a trigonal prismatic {Gd7} molecular nanomagnet.

Authors:  Eufemio Moreno Pineda; Giulia Lorusso; Karzan H Zangana; Elias Palacios; Jürgen Schnack; Marco Evangelisti; Richard E P Winpenny; Eric J L McInnes
Journal:  Chem Sci       Date:  2016-04-25       Impact factor: 9.825

7.  3-Pyridylacetic-Based Lanthanide Complexes Exhibiting Magnetic Entropy Changes, Single-Molecule Magnet, and Fluorescence.

Authors:  Ying-Bing Lu; Jun-Wei Wu; Shui-Dong Zhu; Sheng-Qian Wang; Shi-Yong Zhang; Cai-Ming Liu; Rong Li; Juan Li; Jia-Hao Ai; Yong-Rong Xie
Journal:  ACS Omega       Date:  2022-01-11

8.  Investigations of the Magnetocaloric and Thermal Expansion Properties of the Ln3(adipate)4.5(DMF)2 (Ln = Gd-Er) Framework Series.

Authors:  Patrick W Doheny; Simon J Cassidy; Paul J Saines
Journal:  Inorg Chem       Date:  2022-03-14       Impact factor: 5.165

9.  Layered gadolinium hydroxides for low-temperature magnetic cooling.

Authors:  Gonzalo Abellán; Guillermo Mínguez Espallargas; Giulia Lorusso; Marco Evangelisti; Eugenio Coronado
Journal:  Chem Commun (Camb)       Date:  2015-08-10       Impact factor: 6.222

10.  Liquid phase blending of metal-organic frameworks.

Authors:  Louis Longley; Sean M Collins; Chao Zhou; Glen J Smales; Sarah E Norman; Nick J Brownbill; Christopher W Ashling; Philip A Chater; Robert Tovey; Carola-Bibiane Schönlieb; Thomas F Headen; Nicholas J Terrill; Yuanzheng Yue; Andrew J Smith; Frédéric Blanc; David A Keen; Paul A Midgley; Thomas D Bennett
Journal:  Nat Commun       Date:  2018-06-15       Impact factor: 14.919
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