Literature DB >> 23804537

Selective C(sp2)-C(sp) bond cleavage: the nitrogenation of alkynes to amides.

Chong Qin1, Peng Feng, Yang Ou, Tao Shen, Teng Wang, Ning Jiao.   

Abstract

Breakthrough: A novel catalyzed direct highly selective C(sp2)-C(sp) bond functionalization of alkynes to amides has been developed. Nitrogenation is achieved by the highly selective C(sp2)-C(sp) bond cleavage of aryl-substituted alkynes. The oxidant-free and mild conditions and wide substrate scope make this method very practical.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  CC bond cleavage; alkynes; amides; gold; rearrangement

Mesh：

Substances：

Year:  2013        PMID： 23804537     DOI： 10.1002/anie.201303376

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Meeting the challenge of intermolecular gold(I)-catalyzed cycloadditions of alkynes and allenes.

Authors:  Michael E Muratore; Anna Homs; Carla Obradors; Antonio M Echavarren
Journal:  Chem Asian J       Date:  2014-07-22

2.  Silver-Catalyzed Stereoselective Aminosulfonylation of Alkynes.

Authors:  Yongquan Ning; Qinghe Ji; Peiqiu Liao; Edward A Anderson; Xihe Bi
Journal:  Angew Chem Int Ed Engl       Date:  2017-07-07       Impact factor: 15.336

Review 3.  Metal-Catalysed Azidation of Organic Molecules.

Authors:  Monalisa Goswami; Bas de Bruin
Journal:  European J Org Chem       Date:  2016-12-22

4.  Visible light-mediated photocatalytic oxidative cleavage of activated alkynes via hydroamination: a direct approach to oxamates.

Authors:  Narenderreddy Katta; Mamata Ojha; Arumugavel Murugan; Sagar Arepally; Duddu S Sharada
Journal:  RSC Adv       Date:  2020-03-27       Impact factor: 3.361

5.  Comparative secretome of white-rot fungi reveals co-regulated carbohydrate-active enzymes associated with selective ligninolysis of ramie stalks.

Authors:  Chunliang Xie; Wenbing Gong; Zuohua Zhu; Yingjun Zhou; Chao Xu; Li Yan; Zhenxiu Hu; Lianzhong Ai; Yuande Peng
Journal:  Microb Biotechnol       Date:  2020-08-14       Impact factor: 5.813
  5 in total

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