Literature DB >> 23784864

An azobenzene unit embedded in a cyclopeptide as a type-specific and spatially directed switch.

Gebhard Haberhauer1, Christine Kallweit, Christoph Wölper, Dieter Bläser.   

Abstract

By embedding an azobenzene unit into a chiral scaffold, switching of azobenzene from the trans-(P) isomer to the cis-(P) isomer and back was achieved (black arrows in picture). The embedding leads to a flipping process in which the phenyl rings can only move directly towards one another in the switching process.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  azo compounds; circular dichroism; isomerization; molecular switches; photochemistry

Mesh:

Substances:

Year:  2013        PMID: 23784864     DOI: 10.1002/anie.201301516

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  2 in total

Review 1.  Artificial Molecular Machines.

Authors:  Sundus Erbas-Cakmak; David A Leigh; Charlie T McTernan; Alina L Nussbaumer
Journal:  Chem Rev       Date:  2015-09-08       Impact factor: 60.622

2.  Influence of Chromophoric Electron-Donating Groups on Photoinduced Solid-to-Liquid Transitions of Azopolymers.

Authors:  Jian Xu; Bin Niu; Song Guo; Xiaolei Zhao; Xiaoli Li; Jinwen Peng; Weixing Deng; Si Wu; Yuanli Liu
Journal:  Polymers (Basel)       Date:  2020-04-13       Impact factor: 4.329

  2 in total

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