Literature DB >> 23782172

Synthesis of highly cis, syndiotactic polymers via ring-opening metathesis polymerization using ruthenium metathesis catalysts.

Lauren E Rosebrugh1, Vanessa M Marx, Benjamin K Keitz, Robert H Grubbs.   

Abstract

The first example of ruthenium-mediated ring-opening metathesis polymerization generating highly cis, highly tactic polymers is reported. While the cis content varied from 62 to >95% depending on the monomer structure, many of the polymers synthesized displayed high tacticity (>95%). Polymerization of an enantiomerically pure 2,3-dicarboalkoxynorbornadiene revealed a syndiotactic microstructure.

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Year:  2013        PMID： 23782172      PMCID： PMC3773019          DOI： 10.1021/ja405559y

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  13 in total

1.  Mechanism and activity of ruthenium olefin metathesis catalysts.

Authors:  M S Sanford; J A Love; R H Grubbs
Journal:  J Am Chem Soc       Date:  2001-07-11       Impact factor: 15.419

2.  Scope of the ring-opening metathesis polymerization (ROMP) reaction of 1-substituted cyclobutenes.

Authors:  Airong Song; Jae Chul Lee; Kathlyn A Parker; Nicole S Sampson
Journal:  J Am Chem Soc       Date:  2010-08-04       Impact factor: 15.419

3.  Chelated ruthenium catalysts for Z-selective olefin metathesis.

Authors:  Koji Endo; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2011-05-12       Impact factor: 15.419

4.  Regio- and stereoselective ring-opening metathesis polymerization of 3-substituted cyclooctenes.

Authors:  Shingo Kobayashi; Louis M Pitet; Marc A Hillmyer
Journal:  J Am Chem Soc       Date:  2011-03-29       Impact factor: 15.419

5.  Cis-selective ring-opening metathesis polymerization with ruthenium catalysts.

Authors:  Benjamin K Keitz; Alexey Fedorov; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2012-01-20       Impact factor: 15.419

6.  Synthesis of stereoregular ROMP polymers using molybdenum and tungsten imido alkylidene initiators.

Authors:  Richard R Schrock
Journal:  Dalton Trans       Date:  2011-05-05       Impact factor: 4.390

7.  Improved ruthenium catalysts for Z-selective olefin metathesis.

Authors:  Benjamin K Keitz; Koji Endo; Paresma R Patel; Myles B Herbert; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2011-12-09       Impact factor: 15.419

8.  Highly active ruthenium metathesis catalysts exhibiting unprecedented activity and Z-selectivity.

Authors:  Lauren E Rosebrugh; Myles B Herbert; Vanessa M Marx; Benjamin K Keitz; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2013-01-17       Impact factor: 15.419

9.  On the tacticity of polynorbornenes with 5,6-endo pendant groups that contain substituted aryl chromophores.

Authors:  Wei-Yu Lin; Hsian-Wen Wang; Zhi-Chang Liu; Jun Xu; Chih-Wei Chen; Yun-Chin Yang; Shou-Ling Huang; Hsiao-Ching Yang; Tien-Yau Luh
Journal:  Chem Asian J       Date:  2007-06-04

10.  Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex.

Authors:  Margaret M Flook; Annie J Jiang; Richard R Schrock; Peter Müller; Amir H Hoveyda
Journal:  J Am Chem Soc       Date:  2009-06-17       Impact factor: 15.419
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  9 in total

Review 1.  Recent advances in ruthenium-based olefin metathesis.

Authors:  O M Ogba; N C Warner; D J O'Leary; R H Grubbs
Journal:  Chem Soc Rev       Date:  2018-06-18       Impact factor: 54.564

2.  Tandem Z-Selective Cross-Metathesis/Dihydroxylation: Synthesis of anti-1,2-Diols.

Authors:  Peter K Dornan; Zachary K Wickens; Robert H Grubbs
Journal:  Angew Chem Int Ed Engl       Date:  2015-04-27       Impact factor: 15.336

3.  Self-assembly of random copolymers.

Authors:  Longyu Li; Kishore Raghupathi; Cunfeng Song; Priyaa Prasad; S Thayumanavan
Journal:  Chem Commun (Camb)       Date:  2014-11-14       Impact factor: 6.222

4.  Enantioselective olefin metathesis with cyclometalated ruthenium complexes.

Authors:  John Hartung; Peter K Dornan; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2014-09-02       Impact factor: 15.419

5.  Ruthenium-catalysed Z-selective cross metathesis of allylic-substituted olefins.

Authors:  Brendan L Quigley; Robert H Grubbs
Journal:  Chem Sci       Date:  2014-02       Impact factor: 9.825

Review 6.  Recent advances in metathesis-derived polymers containing transition metals in the side chain.

Authors:  Ileana Dragutan; Valerian Dragutan; Bogdan C Simionescu; Albert Demonceau; Helmut Fischer
Journal:  Beilstein J Org Chem       Date:  2015-12-28       Impact factor: 2.883

7.  General approach to the synthesis of the chlorosulfolipids danicalipin A, mytilipin A, and malhamensilipin A in enantioenriched form.

Authors:  Won-jin Chung; Joseph S Carlson; Christopher D Vanderwal
Journal:  J Org Chem       Date:  2014-02-13       Impact factor: 4.354

8.  Carboxylate-assisted C(sp³)-H activation in olefin metathesis-relevant ruthenium complexes.

Authors:  Jeffrey S Cannon; Lufeng Zou; Peng Liu; Yu Lan; Daniel J O'Leary; K N Houk; Robert H Grubbs
Journal:  J Am Chem Soc       Date:  2014-04-25       Impact factor: 15.419

9.  Cationic ruthenium alkylidene catalysts bearing phosphine ligands.

Authors:  Koji Endo; Robert H Grubbs
Journal:  Dalton Trans       Date:  2016-02-28       Impact factor: 4.390
  9 in total

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