| Literature DB >> 23780919 |
N Acerbi1, S C Edman Tsang, G Jones, S Golunski, P Collier.
Abstract
A correlation between ceria reducibility and the precious-metal d-band center is reported for ceria-supported precious-metal catalysts. The results could provide the missing link to fully explain the occurrence of strong metal-support interaction (SMSI) and hydrogen spillover in catalysts that consist of dispersed metals in contact with reducible metal oxides.Entities:
Keywords: ceria; d-band center; electronic effect; redox chemistry; supported catalysts
Year: 2013 PMID： 23780919 DOI： 10.1002/anie.201300130
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336