Literature DB >> 23780699

Evidence for low-temperature melting of mercury owing to relativity.

Florent Calvo1, Elke Pahl, Michael Wormit, Peter Schwerdtfeger.   

Abstract

An old problem solved: Monte Carlo simulations using the diatomic-in-molecule method derived from accurate ground- and excited-state relativistic calculations for Hg2 show that the melting temperature for bulk mercury is lowered by 105 K, which is due to relativistic effects.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  Monte Carlo simulations; melting; mercury; relativistic effects

Year:  2013        PMID: 23780699     DOI: 10.1002/anie.201302742

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  4 in total

1.  Mesmerized by mercury.

Authors:  Joel D Blum
Journal:  Nat Chem       Date:  2013-12       Impact factor: 24.427

2.  Nuclear chemistry: Lawrencium bridges a knowledge gap.

Authors:  Andreas Türler
Journal:  Nature       Date:  2015-04-09       Impact factor: 49.962

Review 3.  Copernicium: A Relativistic Noble Liquid.

Authors:  Jan-Michael Mewes; Odile R Smits; Georg Kresse; Peter Schwerdtfeger
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-25       Impact factor: 15.336

4.  Exclusively Relativistic: Periodic Trends in the Melting and Boiling Points of Group 12.

Authors:  Jan-Michael Mewes; Peter Schwerdtfeger
Journal:  Angew Chem Int Ed Engl       Date:  2021-02-26       Impact factor: 15.336

  4 in total

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