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Literature DB >> 23775686

Combinations of ethers and B(C6F5)3 function as hydrogenation catalysts.

Lindsay J Hounjet¹, Christoph Bannwarth, Christian N Garon, Christopher B Caputo, Stefan Grimme, Douglas W Stephan.

Abstract

It works ether way: Labile adducts of dialkyl ethers with the electrophilic borane B(C6F5)3 are shown to scramble HD to H2 and D2 and catalyze the hydrogenation of 1,1-diphenylethylene.

Entities: Chemical Disease

Keywords: boranes; ethers; frustrated Lewis pairs; hydrogenation; organocatalysis

Year: 2013 PMID： 23775686 DOI： 10.1002/anie.201303166

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

13 in total

Review 1. Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.

Authors: R Morris Bullock; Geoffrey M Chambers
Journal: Philos Trans A Math Phys Eng Sci Date: 2017-08-28 Impact factor: 4.226

2. Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si-F Bonds.

Authors: Florian S Tschernuth; Thaddäus Thorwart; Lutz Greb; Franziska Hanusch; Shigeyoshi Inoue
Journal: Angew Chem Int Ed Engl Date: 2021-11-05 Impact factor: 16.823

3. Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes.

Authors: Renyuan Pony Yu; Jonathan M Darmon; Carsten Milsmann; Grant W Margulieux; S Chantal E Stieber; Serena DeBeer; Paul J Chirik
Journal: J Am Chem Soc Date: 2013-08-22 Impact factor: 15.419

4. Optimizing the Energetics of FLP-Type H₂ Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

Authors: Mojgan Heshmat; Bernd Ensing
Journal: J Phys Chem A Date: 2020-07-29 Impact factor: 2.781

Combinations of ethers and B(C6F5)3 function as hydrogenation catalysts.

Review 1. Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes.

2. Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si-F Bonds.

3. Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes.

4. Optimizing the Energetics of FLP-Type H₂ Activation by Modulating the Electronic and Structural Properties of the Lewis Acids: A DFT Study.

5. Metal-free hydrogenation catalyzed by an air-stable borane: use of solvent as a frustrated Lewis base.

6. Be₁₂O₁₂ Nano-cage as a Promising Catalyst for CO₂ Hydrogenation.

7. Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines.

8. Hydrogen activation using a novel tribenzyltin Lewis acid.

9. Heterolytic Splitting of Molecular Hydrogen by Frustrated and Classical Lewis Pairs: A Unified Reactivity Concept.

10. A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis.