Literature DB >> 23765380

Structural and electronic studies of metal carbide clusterfullerene Sc2C2@Cs-C72.

Yongqiang Feng1, Taishan Wang, Jingyi Wu, Lai Feng, Junfeng Xiang, Yihan Ma, Zhuxia Zhang, Li Jiang, Chunying Shu, Chunru Wang.   

Abstract

We present a metal carbide clusterfullerene Sc2C2@Cs(10528)-C72, whose structure has been baffling for many years. A motional endohedral Sc2C2 cluster, special molecule geometry and electronic structure were found in Sc2C2@Cs(10528)-C72. The paramagnetic Sc2C2@Cs-C72 anion radical was successfully prepared by a chemical reduction method and hyperfine couplings in the ESR spectrum were observed.

Entities:  

Year:  2013        PMID： 23765380     DOI： 10.1039/c3nr01739g

Source DB:  PubMed          Journal:  Nanoscale        ISSN： 2040-3364            Impact factor:   7.790


  3 in total

1.  Shape-adaptive single-molecule magnetism and hysteresis up to 14 K in oxide clusterfullerenes Dy2O@C72 and Dy2O@C74 with fused pentagon pairs and flexible Dy-(μ2-O)-Dy angle.

Authors:  Georgios Velkos; Wei Yang; Yang-Rong Yao; Svetlana M Sudarkova; XinYe Liu; Bernd Büchner; Stanislav M Avdoshenko; Ning Chen; Alexey A Popov
Journal:  Chem Sci       Date:  2020-04-20       Impact factor: 9.825

2.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236

3.  Eu@C72: Computed Comparable Populations of Two Non-IPR Isomers.

Authors:  Zdeněk Slanina; Filip Uhlík; Shigeru Nagase; Takeshi Akasaka; Ludwik Adamowicz; Xing Lu
Journal:  Molecules       Date:  2017-06-24       Impact factor: 4.411
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.