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Literature DB >> 23765069

Preparation of a semiquinonate-bridged diiron(II) complex and elucidation of its geometric and electronic structures.

Amanda E Baum¹, Sergey V Lindeman, Adam T Fiedler.

Abstract

The synthesis and crystal structure of a diiron(II) complex containing a bridging semiquinonate radical are presented. The unique electronic structure of this S = 7/2 complex is examined with spectroscopic (absorption, EPR, resonance Raman) and computational methods.

Entities: Chemical Disease Gene Species

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Year: 2013 PMID： 23765069 PMCID： PMC3860832 DOI： 10.1039/c3cc42980f

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

20 in total

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10. The semiquinone-iron complex of photosystem II: structural insights from ESR and theoretical simulation; evidence that the native ligand to the non-heme iron is carbonate.

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