Literature DB >> 23761938

Continuous-Wave Operation of a Frequency-Tunable 460-GHz Second-Harmonic Gyrotron for Enhanced Nuclear Magnetic Resonance.

Antonio C Torrezan1, Seong-Tae Han, Ivan Mastovsky, Michael A Shapiro, Jagadishwar R Sirigiri, Richard J Temkin, Robert G Griffin, Alexander B Barnes.   

Abstract

The design, operation, and characterization of a continuous-wave (CW) tunable second-harmonic 460-GHz gyrotron are reported. The gyrotron is intended to be used as a submillimeter-wave source for 700-MHz nuclear magnetic resonance experiments with sensitivity enhanced by dynamic nuclear polarization. The gyrotron operates in the whispering-gallery mode TE11,2 and has generated 16 W of output power with a 13-kV 100-mA electron beam. The start oscillation current measured over a range of magnetic field values is in good agreement with theoretical start currents obtained from linear theory for successive high-order axial modes TE11,2,q. The minimum start current is 27 mA. Power and frequency tuning measurements as a function of the electron cyclotron frequency have also been carried out. A smooth frequency tuning range of 1 GHz was obtained for the operating second-harmonic mode either by magnetic field tuning or beam voltage tuning. Long-term CW operation was evaluated during an uninterrupted period of 48 h, where the gyrotron output power and frequency were kept stable to within ±0.7% and ±6 ppm, respectively, by a computerized control system. Proper operation of an internal quasi-optical mode converter implemented to transform the operating whispering-gallery mode to a Gaussian-like beam was also verified. Based on the images of the gyrotron output beam taken with a pyroelectric camera, the Gaussian-like mode content of the output beam was computed to be 92% with an ellipticity of 12%.

Entities:  

Keywords:  Dynamic nuclear polarization (DNP); nuclear magnetic resonance (NMR); second cyclotron harmonic; submillimeter wave; terahertz; tunable gyrotron

Year:  2010        PMID: 23761938      PMCID: PMC3677787     

Source DB:  PubMed          Journal:  IEEE Trans Electron Devices        ISSN: 0018-9383            Impact factor:   2.917


  8 in total

1.  Ultrawide band multifrequency high-field EMR technique: A methodology for increasing spectroscopic information.

Authors:  A K Hassan; L A Pardi; J Krzystek; A Sienkiewicz; P Goy; M Rohrer; L C Brunel
Journal:  J Magn Reson       Date:  2000-02       Impact factor: 2.229

2.  Dynamic nuclear polarization with a cyclotron resonance maser at 5 T.

Authors: 
Journal:  Phys Rev Lett       Date:  1993-11-22       Impact factor: 9.161

Review 3.  Dynamic nuclear polarization at high magnetic fields.

Authors:  Thorsten Maly; Galia T Debelouchina; Vikram S Bajaj; Kan-Nian Hu; Chan-Gyu Joo; Melody L Mak-Jurkauskas; Jagadishwar R Sirigiri; Patrick C A van der Wel; Judith Herzfeld; Richard J Temkin; Robert G Griffin
Journal:  J Chem Phys       Date:  2008-02-07       Impact factor: 3.488

4.  Continuous-Wave Operation of a 460-GHz Second Harmonic Gyrotron Oscillator.

Authors:  Melissa K Hornstein; Vikram S Bajaj; Robert G Griffin; Richard J Temkin
Journal:  IEEE Trans Plasma Sci IEEE Nucl Plasma Sci Soc       Date:  2006-06       Impact factor: 1.222

5.  Operational Characteristics of a 14-W 140-GHz Gyrotron for Dynamic Nuclear Polarization.

Authors:  Colin D Joye; Robert G Griffin; Melissa K Hornstein; Kan-Nian Hu; Kenneth E Kreischer; Melanie Rosay; Michael A Shapiro; Jagadishwar R Sirigiri; Richard J Temkin; Paul P Woskov
Journal:  IEEE Trans Plasma Sci IEEE Nucl Plasma Sci Soc       Date:  2006-06       Impact factor: 1.222

6.  In situ temperature jump high-frequency dynamic nuclear polarization experiments: enhanced sensitivity in liquid-state NMR spectroscopy.

Authors:  Chan-Gyu Joo; Kan-Nian Hu; Jeffrey A Bryant; Robert G Griffin
Journal:  J Am Chem Soc       Date:  2006-07-26       Impact factor: 15.419

7.  250GHz CW gyrotron oscillator for dynamic nuclear polarization in biological solid state NMR.

Authors:  Vikram S Bajaj; Melissa K Hornstein; Kenneth E Kreischer; Jagadishwar R Sirigiri; Paul P Woskov; Melody L Mak-Jurkauskas; Judith Herzfeld; Richard J Temkin; Robert G Griffin
Journal:  J Magn Reson       Date:  2007-09-20       Impact factor: 2.229

8.  Corrugated Waveguide and Directional Coupler for CW 250-GHz Gyrotron DNP Experiments.

Authors:  Paul P Woskov; Vikram S Bajaj; Melissa K Hornstein; Richard J Temkin; Robert G Griffin
Journal:  IEEE Trans Microw Theory Tech       Date:  2005-06       Impact factor: 3.599

  8 in total
  9 in total

1.  Spectroscopy: Clear signals from surfaces.

Authors:  Robert G Griffin
Journal:  Nature       Date:  2010-11-18       Impact factor: 49.962

2.  THz Dynamic Nuclear Polarization NMR.

Authors:  Emilio A Nanni; Alexander B Barnes; Robert G Griffin; Richard J Temkin
Journal:  IEEE Trans Terahertz Sci Technol       Date:  2011-08-29       Impact factor: 3.274

3.  Frequency swept microwaves for hyperfine decoupling and time domain dynamic nuclear polarization.

Authors:  Daniel E M Hoff; Brice J Albert; Edward P Saliba; Faith J Scott; Eric J Choi; Michael Mardini; Alexander B Barnes
Journal:  Solid State Nucl Magn Reson       Date:  2015-10-09       Impact factor: 2.293

4.  A 250 GHz gyrotron with a 3 GHz tuning bandwidth for dynamic nuclear polarization.

Authors:  Alexander B Barnes; Emilio A Nanni; Judith Herzfeld; Robert G Griffin; Richard J Temkin
Journal:  J Magn Reson       Date:  2012-03-29       Impact factor: 2.229

5.  Simplified THz Instrumentation for High-Field DNP-NMR Spectroscopy.

Authors:  Thorsten Maly; Jagadishwar R Sirigiri
Journal:  Appl Magn Reson       Date:  2012-07-01       Impact factor: 0.831

6.  Overhauser Dynamic Nuclear Polarization with Selectively Deuterated BDPA Radicals.

Authors:  Léo Delage-Laurin; Ravi Shankar Palani; Natalie Golota; Michael Mardini; Yifu Ouyang; Kong Ooi Tan; Timothy M Swager; Robert G Griffin
Journal:  J Am Chem Soc       Date:  2021-11-23       Impact factor: 15.419

7.  Continuously Tunable 250 GHz Gyrotron with a Double Disk Window for DNP-NMR Spectroscopy.

Authors:  Sudheer Jawla; Qing Zhe Ni; Alexander Barnes; William Guss; Eugenio Daviso; Judith Herzfeld; Robert Griffin; Richard Temkin
Journal:  J Infrared Millim Terahertz Waves       Date:  2012-11-15       Impact factor: 1.768

8.  Dynamic nuclear polarization at 700 MHz/460 GHz.

Authors:  Alexander B Barnes; Evgeny Markhasin; Eugenio Daviso; Vladimir K Michaelis; Emilio A Nanni; Sudheer K Jawla; Elijah L Mena; Ronald DeRocher; Ajay Thakkar; Paul P Woskov; Judith Herzfeld; Richard J Temkin; Robert G Griffin
Journal:  J Magn Reson       Date:  2012-08-14       Impact factor: 2.229

9.  A quasi-optical and corrugated waveguide microwave transmission system for simultaneous dynamic nuclear polarization NMR on two separate 14.1 T spectrometers.

Authors:  Thierry Dubroca; Adam N Smith; Kevin J Pike; Stuart Froud; Richard Wylde; Bianca Trociewitz; Johannes McKay; Frederic Mentink-Vigier; Johan van Tol; Sungsool Wi; William Brey; Joanna R Long; Lucio Frydman; Stephen Hill
Journal:  J Magn Reson       Date:  2018-01-31       Impact factor: 2.229

  9 in total

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