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Literature DB >> 23758209

Cu-catalyzed mild C(sp2)-H functionalization assisted by carboxylic acids en route to hydroxylated arenes.

Abstract

A formal Cu-catalyzed C(sp(2))-H hydroxylation assisted by benzoic acids is described. The procedure is characterized by its mild reaction conditions and wide substrate scope utilizing simple and cheap Cu catalysts, thus becoming a user-friendly and operationally simple protocol for C(sp(2))-H hydroxylation.

Entities: Chemical Gene

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Year: 2013 PMID： 23758209 DOI： 10.1021/ja4047894

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

11 in total

1. General and practical carboxyl-group-directed remote C-H oxygenation reactions of arenes.

Authors: Yang Wang; Anton V Gulevich; Vladimir Gevorgyan
Journal: Chemistry Date: 2013-10-21 Impact factor: 5.236

2. Chemo- and regioselective benzylic C(sp³)-H oxidation bridging the gap between hetero- and homogeneous copper catalysis.

Authors: Shantanu Nandi; Shuvam Mondal; Ranjan Jana
Journal: iScience Date: 2022-05-02

3. Copper-catalyzed etherification of arene C-H bonds.

Authors: James Roane; Olafs Daugulis
Journal: Org Lett Date: 2013-11-01 Impact factor: 6.005

4. Copper-catalyzed C-H acyloxylation of 2-phenylpyridine using oxygen as the oxidant.

Authors: Feifan Wang; Zhiyang Lin; Weisheng Yu; Qingdong Hu; Chao Shu; Wu Zhang
Journal: RSC Adv Date: 2018-05-03 Impact factor: 3.361

Review 5. Electrochemistry and Photoredox Catalysis: A Comparative Evaluation in Organic Synthesis.

Authors: Rik H Verschueren; Wim M De Borggraeve
Journal: Molecules Date: 2019-06-05 Impact factor: 4.411

6. Tertiary amine-directed and involved carbonylative cyclizations through Pd/Cu-cocatalyzed multiple C-X (X = H or N) bond cleavage.

Authors: Qiu-Chao Mu; Yi-Xue Nie; Xing-Feng Bai; Jing Chen; Lei Yang; Zheng Xu; Li Li; Chun-Gu Xia; Li-Wen Xu
Journal: Chem Sci Date: 2019-08-19 Impact factor: 9.825

Cu-catalyzed mild C(sp2)-H functionalization assisted by carboxylic acids en route to hydroxylated arenes.

1. General and practical carboxyl-group-directed remote C-H oxygenation reactions of arenes.

2. Chemo- and regioselective benzylic C(sp³)-H oxidation bridging the gap between hetero- and homogeneous copper catalysis.

3. Copper-catalyzed etherification of arene C-H bonds.

4. Copper-catalyzed C-H acyloxylation of 2-phenylpyridine using oxygen as the oxidant.

Review 5. Electrochemistry and Photoredox Catalysis: A Comparative Evaluation in Organic Synthesis.

6. Tertiary amine-directed and involved carbonylative cyclizations through Pd/Cu-cocatalyzed multiple C-X (X = H or N) bond cleavage.

7. Chrysomycin A Derivatives for the Treatment of Multi-Drug-Resistant Tuberculosis.

8. Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp(2))-H activation/C-O formation.

9. Identification of monodentate oxazoline as a ligand for copper-promoted ortho-C-H hydroxylation and amination.

10. Directing group assisted meta-hydroxylation by C-H activation.