Literature DB >> 23752140

Structural and spectroscopic characterization of potassium fluoroborohydrides.

Richard H Heyn1, Ivan Saldan, Magnus H Sørby, Christoph Frommen, Bjørnar Arstad, Aud M Bougza, Helmer Fjellvåg, Bjørn C Hauback.   

Abstract

Mechanochemical reactions between KBH4 and KBF4 result in the formation of potassium fluoroborohydrides K(BH(x)F(4-x)) (x = 0-4), as determined by (11)B and (19)F solid state NMR. The materials maintain the cubic KBH4 structure. Thermogravimetric (TG) data for a ball-milled sample with KBH4 : KBF4 = 3 : 1 are consistent with only desorption of hydrogen.

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Year:  2013        PMID: 23752140     DOI: 10.1039/c3cp52070f

Source DB:  PubMed          Journal:  Phys Chem Chem Phys        ISSN: 1463-9076            Impact factor:   3.676


  1 in total

1.  Effects of LiBF4 Addition on the Lithium-Ion Conductivity of LiBH4.

Authors:  Laura M de Kort; Valerio Gulino; Didier Blanchard; Peter Ngene
Journal:  Molecules       Date:  2022-03-28       Impact factor: 4.411

  1 in total

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