| Literature DB >> 23748437 |
Kim Søholm Halskov1, Tricia Naicker, Magnus E Jensen, Karl Anker Jørgensen.
Abstract
Highly regio- and stereoselective remote aziridination of 2,4-dienals has been developed, based on a vinylogous iminium-ion-dienamine catalytic cascade reaction. Transformations of the aziridine products into enantioenriched motifs are also demonstrated. Furthermore, the reaction concept is extended to include enantioselective 1,6-addition of thiols.Entities:
Year: 2013 PMID: 23748437 DOI: 10.1039/c3cc43506g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222