Phuong V Dau1, Seth M Cohen. 1. Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, CA 92093, USA.
Abstract
Metal-organic frameworks (MOFs) functionalized via Ir(I) cyclometalation are shown to be effective as heterogeneous catalysts for the allylic N-alkylation of various amines. The MOF catalysts are one of the first and most effective MOF-based heterogeneous organometallic catalysts for the direct formation of C-N bonds. In addition, these MOFs represent a rare, stable and reusable, class of reactive Ir catalysts.
Metal-organic frameworks (MOFs) functionalized via Ir(I) cyclon class="Chemical">metalation are shown to be effective as heterogeneous catalysts for the allylic N-alkylation of various amines. The MOF catalysts are one of the first and most effective MOF-based heterogeneous organometallic catalysts for the direct formation of C-N bonds. In addition, these MOFs represent a rare, stable and reusable, class of reactive Ir catalysts.
Authors: Piwai Tshuma; Banothile C E Makhubela; Lars Öhrström; Susan A Bourne; Nabanita Chatterjee; Isaac N Beas; James Darkwa; Gift Mehlana Journal: RSC Adv Date: 2020-01-22 Impact factor: 4.036