Literature DB >> 23730689

Copper-catalyzed sulfonamides formation from sodium sulfinates and amines.

Xiaodong Tang1, Liangbin Huang, Chaorong Qi, Xia Wu, Wanqing Wu, Huanfeng Jiang.   

Abstract

A new and convenient method for the construction of sulfonamides via a copper-catalyzed oxidative coupling between sodium sulfinates and amines with 1 atm O2 or DMSO as the oxidant was described. This method provides efficient and robust synthesis of functional sulfonamides in good yields and excellent chemoselectivity. And detailed mechanistic studies showed that this transformation may go through a single electron transfer (SET) pathway.

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Year:  2013        PMID： 23730689     DOI： 10.1039/c3cc41249k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  11 in total

1.  Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives.

Authors:  Miles W Johnson; Scott W Bagley; Neal P Mankad; Robert G Bergman; Vincent Mascitti; F Dean Toste
Journal:  Angew Chem Int Ed Engl       Date:  2014-03-20       Impact factor: 15.336

Review 2.  Synthesis and applications of sodium sulfinates (RSO2Na): a powerful building block for the synthesis of organosulfur compounds.

Authors:  Raju Jannapu Reddy; Arram Haritha Kumari
Journal:  RSC Adv       Date:  2021-03-01       Impact factor: 3.361

3.  Iodine-catalyzed sulfonylation of sulfonyl hydrazides with tert-amines: a green and efficient protocol for the synthesis of sulfonamides.

Authors:  Jinyang Chen; Xiaoran Han; Lan Mei; Jinchuan Liu; Kui Du; Tuanwu Cao; Qiang Li
Journal:  RSC Adv       Date:  2019-10-02       Impact factor: 4.036

Review 4.  Sulfur Containing Scaffolds in Drugs: Synthesis and Application in Medicinal Chemistry.

Authors:  Minghao Feng; Bingqing Tang; Steven H Liang; Xuefeng Jiang
Journal:  Curr Top Med Chem       Date:  2016       Impact factor: 3.295

5.  Ligand-Mediated and Copper-Catalyzed C(sp(3))-H Bond Functionalization of Aryl Ketones with Sodium Sulfinates under Mild Conditions.

Authors:  Xing-Wang Lan; Nai-Xing Wang; Cui-Bing Bai; Wei Zhang; Yalan Xing; Jia-Long Wen; Yan-Jing Wang; Yi-He Li
Journal:  Sci Rep       Date:  2015-12-18       Impact factor: 4.379

6.  A tunable pair electrochemical strategy for the synthesis of new benzenesulfonamide derivatives.

Authors:  Banafsheh Mokhtari; Davood Nematollahi; Hamid Salehzadeh
Journal:  Sci Rep       Date:  2019-03-14       Impact factor: 4.379

7.  Selective Late-Stage Sulfonyl Chloride Formation from Sulfonamides Enabled by Pyry-BF4.

Authors:  Alejandro Gómez-Palomino; Josep Cornella
Journal:  Angew Chem Int Ed Engl       Date:  2019-10-28       Impact factor: 15.336

8.  The Three-Component Synthesis of 4-Sulfonyl-1,2,3-triazoles via a Sequential Aerobic Copper-Catalyzed Sulfonylation and Dimroth Cyclization.

Authors:  Max Van Hoof; Santhini Pulikkal Veettil; Wim Dehaen
Journal:  Molecules       Date:  2021-01-22       Impact factor: 4.411

9.  Copper-assisted preparation of pyridinyl sulfonate esters from hydroxypyridines and sodium sulfinates.

Authors:  Qian Li; Haibo Zhu; Yishuai Liu; Liu Yang; Qiangwen Fan; Zongbo Xie; Zhang-Gao Le
Journal:  RSC Adv       Date:  2022-01-20       Impact factor: 3.361

Review 10.  Direct sulfonamidation of (hetero)aromatic C-H bonds with sulfonyl azides: a novel and efficient route to N-(hetero)aryl sulfonamides.

Authors:  Zhi Liu; Abdolghaffar Ebadi; Mohsen Toughani; Nihat Mert; Esmail Vessally
Journal:  RSC Adv       Date:  2020-10-08       Impact factor: 4.036
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