Literature DB >> 23724828

Surface control of alkyl chain conformations and 2D chiral amplification.

Nadine Hauptmann1, Katharina Scheil, Thiruvancheril G Gopakumar, Franziska L Otte, Christian Schütt, Rainer Herges, Richard Berndt.   

Abstract

Trioctyl-functionalized triazatriangulenium (trioctyl-TATA) deposited on Au(111) and Ag(111) surfaces by electrospray ionization was investigated using low-temperature scanning tunneling microscopy. The molecule surprisingly adsorbs with gauche rather than anti conformations of the octyl groups. We observed chiral amplification in the islands. Only one of the eight possible configurations of the octyl groups was found in homochiral hexagonal networks. Quantum-chemical calculations confirmed and explained the preference for the gauche conformations of adsorbed trioctyl-TATA.

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Year:  2013        PMID： 23724828     DOI： 10.1021/ja4036187

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

1.  Assembling molecular Sierpiński triangle fractals.

Authors:  Jian Shang; Yongfeng Wang; Min Chen; Jingxin Dai; Xiong Zhou; Julian Kuttner; Gerhard Hilt; Xiang Shao; J Michael Gottfried; Kai Wu
Journal:  Nat Chem       Date:  2015-03-30       Impact factor: 24.427

2.  DRILL Interface Makes Ion Soft Landing Broadly Accessible for Energy Science and Applications.

Authors:  Grant E Johnson; Venkateshkumar Prabhakaran; Nigel D Browning; B Layla Mehdi; Julia Laskin; Peter A Kottke; Andrei G Fedorov
Journal:  Batter Supercaps       Date:  2018-06-22

3.  Navigate Flying Molecular Elephants Safely to the Ground: Mass-Selective Soft Landing up to the Mega-Dalton Range by Electrospray Controlled Ion-Beam Deposition.

Authors:  Andreas Walz; Karolina Stoiber; Annette Huettig; Hartmut Schlichting; Johannes V Barth
Journal:  Anal Chem       Date:  2022-05-24       Impact factor: 8.008

4.  Complex Chiral Induction Processes at the Solution/Solid Interface.

Authors:  Hai Cao; Iris Destoop; Kazukuni Tahara; Yoshito Tobe; Kunal S Mali; Steven De Feyter
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2016-07-27       Impact factor: 4.126

5.  Fabrication of 2D Hetero-Complexes With Nucleic-Acid-Base Adenine and Fatty-Acid Stearic Acid at Liquid/Solid Interface.

Authors:  Huiling Zhao; Qian Yang; Zegao Wang; Hang Zhao; Bo Liu; Qianming Chen; Mingdong Dong
Journal:  Front Chem       Date:  2019-07-25       Impact factor: 5.221

6.  Depositing Molecular Graphene Nanoribbons on Ag(111) by Electrospray Controlled Ion Beam Deposition: Self-Assembly and On-Surface Transformations.

Authors:  Wei Ran; Andreas Walz; Karolina Stoiber; Peter Knecht; Hongxiang Xu; Anthoula C Papageorgiou; Annette Huettig; Diego Cortizo-Lacalle; Juan P Mora-Fuentes; Aurelio Mateo-Alonso; Hartmut Schlichting; Joachim Reichert; Johannes V Barth
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-16       Impact factor: 16.823

7.  Electrospray deposition of organic molecules on bulk insulator surfaces.

Authors:  Antoine Hinaut; Rémy Pawlak; Ernst Meyer; Thilo Glatzel
Journal:  Beilstein J Nanotechnol       Date:  2015-09-18       Impact factor: 3.649
  7 in total

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