Ethyl (E)-2-cyano-3-(4-methyl-phen-yl)acrylate: a second monoclinic polymorph.

The title compound, C13H13NO2, was previously described in space group P21/c by He et al. [Acta Cryst. (1993), C49, 2000-2002]. The ethyl group is disordered over two sets of sites in a 0.615 (10):0.385 (10) ratio. The C-O-C-C torsion angles containing the ethyl group are -111.6 (10) and 177.9 (7)°, while in the previously reported polymorph, the torsion angle is -167.3 (2)°. The molecules pack to form a three-dimensional structure in the ABAB style along the c-axis direction in the title compound, but parallel to the a-axis direction in the reported polymorph.

Related literature

For the first polymorph, see: He et al. (1993 ▶). For background to intra­molecular charge-transfer mol­ecules and their use in the construction of one- to three-dimesional organic nanostructures, see: Zhang et al. (2007 ▶); Zhang et al. (2008 ▶).

Experimental

Crystal data

C13H13NO2

M = 215.24

Monoclinic,

a = 4.7616 (4) Å

b = 17.7989 (15) Å

c = 14.2841 (12) Å

β = 93.8021 (10)°

V = 1207.93 (18) Å3

Z = 4

Mo Kα radiation

μ = 0.08 mm−1

T = 298 K

0.20 × 0.20 × 0.20 mm

Data collection

Bruker APEXII CCD diffractometer

Absorption correction: multi-scan phi and omega scans T min = 0.984, T max = 0.984

8359 measured reflections

2117 independent reflections

1617 reflections with I > 2σ(I)

R int = 0.020

Refinement

R[F 2 > 2σ(F 2)] = 0.055

wR(F 2) = 0.192

S = 1.11

2117 reflections

168 parameters

H-atom parameters constrained

Δρmax = 0.19 e Å−3

Δρmin = −0.21 e Å−3

Data collection: APEX2 (Bruker, 2002 ▶); cell refinement: SAINT (Bruker, 2002 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Click here for additional data file.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536813009550/aa2081sup1.cif

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536813009550/aa2081Isup2.mol

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813009550/aa2081Isup3.hkl

Click here for additional data file.

Supplementary material file. DOI: 10.1107/S1600536813009550/aa2081Isup4.cml

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

C13H13NO2	F(000) = 456
Mr = 215.24	Dx = 1.184 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 3950 reflections
a = 4.7616 (4) Å	θ = 2.3–25.5°
b = 17.7989 (15) Å	µ = 0.08 mm−1
c = 14.2841 (12) Å	T = 298 K
β = 93.8021 (10)°	Needle, white
V = 1207.93 (18) Å3	0.20 × 0.20 × 0.20 mm
Z = 4

Bruker APEXII CCD diffractometer	2117 independent reflections
Radiation source: fine-focus sealed tube	1617 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.020
φ and ω scans	θmax = 25.0°, θmin = 1.8°
Absorption correction: multi-scan phi and omega scans	h = −5→5
Tmin = 0.984, Tmax = 0.984	k = −21→19
8359 measured reflections	l = −16→16

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.055	H-atom parameters constrained
wR(F2) = 0.192	w = 1/[σ2(Fo2) + (0.1011P)2 + 0.1786P] where P = (Fo2 + 2Fc2)/3
S = 1.11	(Δ/σ)max < 0.001
2117 reflections	Δρmax = 0.19 e Å−3
168 parameters	Δρmin = −0.21 e Å−3
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.043 (10)

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.2687 (8)	−0.0915 (2)	0.4400 (2)	0.1201 (10)
H1A	0.1208	−0.1263	0.4219	0.180*
H1B	0.2004	−0.0549	0.4823	0.180*
H1C	0.4242	−0.1182	0.4705	0.180*
C2	0.3650 (6)	−0.05220 (16)	0.35330 (19)	0.0954 (8)
C3	0.2589 (7)	0.01687 (16)	0.3251 (2)	0.1062 (9)
H3	0.1250	0.0398	0.3601	0.127*
C4	0.3451 (6)	0.05290 (14)	0.24691 (19)	0.0924 (8)
H4	0.2715	0.0999	0.2307	0.111*
C5	0.5404 (5)	0.02009 (12)	0.19193 (16)	0.0740 (6)
C6	0.6416 (6)	−0.05037 (14)	0.21981 (19)	0.0953 (8)
H6	0.7713	−0.0744	0.1842	0.114*
C7	0.5541 (7)	−0.08526 (15)	0.2988 (2)	0.1009 (9)
H7	0.6256	−0.1324	0.3153	0.121*
C9	0.6075 (5)	0.11983 (12)	0.06603 (15)	0.0713 (6)
C10	0.4199 (5)	0.17670 (12)	0.09614 (16)	0.0777 (7)
C11	0.7662 (5)	0.13621 (14)	−0.01789 (17)	0.0829 (7)
C12	0.741 (3)	0.2242 (6)	−0.1547 (6)	0.109 (3)	0.385 (10)
H12A	0.5727	0.2456	−0.1863	0.131*	0.385 (10)
H12B	0.8083	0.1828	−0.1912	0.131*	0.385 (10)
C13	0.965 (3)	0.2823 (9)	−0.1321 (9)	0.136 (4)	0.385 (10)
H13A	0.8843	0.3244	−0.1017	0.204*	0.385 (10)
H13B	1.0425	0.2987	−0.1890	0.204*	0.385 (10)
H13C	1.1117	0.2608	−0.0911	0.204*	0.385 (10)
C15	0.6509 (5)	0.05304 (12)	0.10882 (16)	0.0755 (6)
H15	0.7755	0.0220	0.0796	0.091*
C12'	0.8890 (16)	0.2220 (4)	−0.1310 (5)	0.0961 (19)	0.615 (10)
H12C	1.0818	0.2271	−0.1053	0.115*	0.615 (10)
H12D	0.8819	0.1840	−0.1797	0.115*	0.615 (10)
C13'	0.780 (2)	0.2953 (3)	−0.1689 (5)	0.119 (2)	0.615 (10)
H13D	0.5833	0.2904	−0.1879	0.178*	0.615 (10)
H13E	0.8814	0.3094	−0.2220	0.178*	0.615 (10)
H13F	0.8040	0.3331	−0.1212	0.178*	0.615 (10)
N1	0.2704 (6)	0.22244 (13)	0.11968 (17)	0.1036 (8)
O1	0.9398 (5)	0.09507 (11)	−0.04727 (14)	0.1101 (7)
O2	0.6971 (4)	0.20214 (10)	−0.05566 (13)	0.1045 (7)

	U11	U22	U33	U12	U13	U23
C1	0.1351 (17)	0.1184 (17)	0.1087 (15)	−0.0055 (14)	0.0237 (13)	0.0261 (13)
C2	0.1080 (15)	0.0895 (14)	0.0898 (13)	−0.0069 (12)	0.0141 (12)	0.0126 (11)
C3	0.123 (2)	0.094 (2)	0.108 (2)	0.0117 (16)	0.0474 (17)	0.0159 (15)
C4	0.1092 (18)	0.0723 (15)	0.0990 (17)	0.0114 (13)	0.0320 (14)	0.0128 (13)
C5	0.0863 (14)	0.0615 (12)	0.0751 (13)	−0.0038 (10)	0.0114 (11)	0.0015 (10)
C6	0.120 (2)	0.0713 (15)	0.0974 (18)	0.0148 (13)	0.0271 (15)	0.0122 (13)
C7	0.131 (2)	0.0749 (16)	0.0985 (18)	0.0101 (14)	0.0183 (16)	0.0203 (14)
C9	0.0841 (13)	0.0612 (12)	0.0695 (12)	−0.0036 (10)	0.0120 (10)	−0.0005 (9)
C10	0.0975 (15)	0.0600 (12)	0.0769 (14)	−0.0010 (11)	0.0151 (11)	0.0059 (10)
C11	0.1033 (17)	0.0688 (14)	0.0783 (14)	0.0001 (12)	0.0191 (12)	0.0043 (11)
C12	0.134 (8)	0.096 (6)	0.099 (6)	0.016 (6)	0.017 (5)	0.014 (4)
C13	0.137 (8)	0.144 (10)	0.132 (8)	−0.025 (8)	0.044 (7)	−0.004 (7)
C15	0.0883 (14)	0.0631 (13)	0.0762 (13)	0.0012 (10)	0.0137 (11)	−0.0020 (10)
C12'	0.104 (4)	0.097 (4)	0.090 (4)	0.011 (4)	0.031 (3)	0.026 (3)
C13'	0.151 (6)	0.101 (4)	0.109 (4)	0.011 (4)	0.042 (4)	0.037 (3)
N1	0.1314 (19)	0.0732 (14)	0.1099 (17)	0.0159 (12)	0.0344 (14)	0.0056 (12)
O1	0.1454 (17)	0.0902 (13)	0.1006 (13)	0.0211 (11)	0.0524 (12)	0.0065 (10)
O2	0.1456 (16)	0.0791 (12)	0.0937 (13)	0.0125 (10)	0.0435 (11)	0.0220 (9)

C1—C2	1.519 (4)	C10—N1	1.147 (3)
C1—H1A	0.9600	C11—O1	1.201 (3)
C1—H1B	0.9600	C11—O2	1.324 (3)
C1—H1C	0.9600	C12—O2	1.496 (8)
C2—C7	1.363 (4)	C12—C13	1.507 (6)
C2—C3	1.379 (4)	C12—H12A	0.9700
C3—C4	1.374 (4)	C12—H12B	0.9700
C3—H3	0.9300	C13—H13A	0.9600
C4—C5	1.385 (3)	C13—H13B	0.9600
C4—H4	0.9300	C13—H13C	0.9600
C5—C6	1.392 (3)	C15—H15	0.9300
C5—C15	1.453 (3)	C12'—C13'	1.492 (5)
C6—C7	1.376 (4)	C12'—O2	1.500 (5)
C6—H6	0.9300	C12'—H12C	0.9700
C7—H7	0.9300	C12'—H12D	0.9700
C9—C15	1.346 (3)	C13'—H13D	0.9600
C9—C10	1.435 (3)	C13'—H13E	0.9600
C9—C11	1.488 (3)	C13'—H13F	0.9600
C2—C1—H1A	109.5	N1—C10—C9	179.5 (3)
C2—C1—H1B	109.5	O1—C11—O2	123.8 (2)
H1A—C1—H1B	109.5	O1—C11—C9	124.1 (2)
C2—C1—H1C	109.5	O2—C11—C9	112.1 (2)
H1A—C1—H1C	109.5	O2—C12—C13	96.8 (8)
H1B—C1—H1C	109.5	O2—C12—H12A	112.4
C7—C2—C3	117.4 (2)	C13—C12—H12A	112.4
C7—C2—C1	120.9 (3)	O2—C12—H12B	112.4
C3—C2—C1	121.6 (3)	C13—C12—H12B	112.4
C4—C3—C2	122.0 (3)	H12A—C12—H12B	110.0
C4—C3—H3	119.0	C9—C15—C5	132.4 (2)
C2—C3—H3	119.0	C9—C15—H15	113.8
C3—C4—C5	120.8 (2)	C5—C15—H15	113.8
C3—C4—H4	119.6	C13'—C12'—O2	104.6 (4)
C5—C4—H4	119.6	C13'—C12'—H12C	110.8
C4—C5—C6	116.7 (2)	O2—C12'—H12C	110.8
C4—C5—C15	125.9 (2)	C13'—C12'—H12D	110.8
C6—C5—C15	117.4 (2)	O2—C12'—H12D	110.8
C7—C6—C5	121.5 (2)	H12C—C12'—H12D	108.9
C7—C6—H6	119.2	C12'—C13'—H13D	109.5
C5—C6—H6	119.2	C12'—C13'—H13E	109.5
C2—C7—C6	121.4 (3)	H13D—C13'—H13E	109.5
C2—C7—H7	119.3	C12'—C13'—H13F	109.5
C6—C7—H7	119.3	H13D—C13'—H13F	109.5
C15—C9—C10	124.5 (2)	H13E—C13'—H13F	109.5
C15—C9—C11	117.9 (2)	C11—O2—C12	124.9 (6)
C10—C9—C11	117.57 (19)	C11—O2—C12'	110.8 (3)
C7—C2—C3—C4	−2.1 (5)	C10—C9—C11—O2	−2.9 (3)
C1—C2—C3—C4	179.9 (3)	C10—C9—C15—C5	−1.5 (4)
C2—C3—C4—C5	1.2 (5)	C11—C9—C15—C5	178.0 (2)
C3—C4—C5—C6	0.2 (4)	C4—C5—C15—C9	2.2 (4)
C3—C4—C5—C15	−178.9 (3)	C6—C5—C15—C9	−177.0 (2)
C4—C5—C6—C7	−0.7 (4)	O1—C11—O2—C12	22.4 (7)
C15—C5—C6—C7	178.5 (2)	C9—C11—O2—C12	−158.7 (6)
C3—C2—C7—C6	1.6 (5)	O1—C11—O2—C12'	−7.2 (5)
C1—C2—C7—C6	179.6 (3)	C9—C11—O2—C12'	171.8 (4)
C5—C6—C7—C2	−0.2 (5)	C13—C12—O2—C11	−111.6 (10)
C15—C9—C11—O1	−3.5 (4)	C13—C12—O2—C12'	−42.2 (9)
C10—C9—C11—O1	176.0 (2)	C13'—C12'—O2—C11	177.9 (7)
C15—C9—C11—O2	177.5 (2)	C13'—C12'—O2—C12	53.2 (10)