Literature DB >> 23723894

5-{4'-[(5-Benzyl-2H-tetra-zol-2-yl)meth-yl]biphenyl-2-yl}-1H-tetra-zole monohydrate.

Gangadhar Y Meti1, S Jeyaseelan, R R Kamble, Atakuri Dorababu, H C Devarajegowda.   

Abstract

In the title compound, C22H18N8·H2O, the dihedral angle between the tetra-zole rings is 69.58 (1)° while the terminal phenyl ring makes dihedral angles of 26.98 (8) and 39.75 (8)° with the other benzene rings. The rings of the biphenyl unit subtend a dihedral angle of 55.23 (8)°. In the crystal, the solvent water mol-ecule is linked to the main mol-ecule via an N-H⋯O hydrogen bond. In addition, C-H⋯N and O-H⋯N hydrogen bonds link the components into chains along [010]. The crystal structure also features C-H⋯π and π-π inter-actions, with centroid-centroid distances of 3.6556 (9) and 3.826 (1) Å.

Entities:  

Year:  2013        PMID: 23723894      PMCID: PMC3648274          DOI: 10.1107/S1600536813009963

Source DB:  PubMed          Journal:  Acta Crystallogr Sect E Struct Rep Online        ISSN: 1600-5368


  2 in total

1.  An improved synthesis of functionalized biphenyl-based phosphine ligands.

Authors:  H Tomori; J M Fox; S L Buchwald
Journal:  J Org Chem       Date:  2000-08-25       Impact factor: 4.354

2.  Synthesis of biphenyl-2-carbonitrile derivatives via a palladium-catalyzed sp2 C-H bond activation using cyano as a directing group.

Authors:  Wu Li; Zhipeng Xu; Peipei Sun; Xiaoqing Jiang; Min Fang
Journal:  Org Lett       Date:  2011-02-21       Impact factor: 6.005

  2 in total

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