Di-μ-cyanido-tetra-cyanido(5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane)[N-(quinolin-8-yl)quinoline-2-carboxamidato]diiron(III)nickel(II) 2.07-hydrate.

The asymmetric unit of the title complex, [Fe2Ni(C19H12N3O)2(CN)6(C16H36N4)]·2.07H2O, contains one [Fe(qcq)(CN)3](-) anion, half a [Ni(teta)](2+) cation and two partially occupied inter-stitial water mol-ecules [qcq(-) is the N-(quinolin-8-yl)quinoline-2-carboxamidate anion and teta is 5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-ne]. In the complex mol-ecule, two [Fe(qcq)(CN)3](-) anions additionally coordinate the central [Ni(teta)](2+) cation through cyanide groups in a trans mode, resulting in a trinuclear structure with the Ni(2+) cation lying on an inversion centre. The two inter-stitial water mol-ecules are partially occupied, with occupancy factors of 0.528 (10) and 0.506 (9). O-H⋯O and O-H⋯N hydrogen bonding involving the two lattice water molecules and the carbonyl function and a teta N atom in an adjacent cluster leads to the formation of layers extending parallel to (010).

Related literature

For the synthesis and background to low-dimensional systems based on modified hexa­cyanido­metalates, see: Liu et al. (2010 ▶); Kim et al. (2009 ▶); Curtis et al. (1964 ▶). For related structures, see: Li et al. (2012 ▶); Panja et al. (2012 ▶).

Experimental

Crystal data

[Fe2Ni(C19H12N3O)2(CN)6(C16H36N4)]·2.07H2O

M = 1244.89

Monoclinic,

a = 9.4145 (13) Å

b = 15.7309 (17) Å

c = 20.590 (2) Å

β = 101.781 (3)°

V = 2985.1 (6) Å3

Z = 2

Mo Kα radiation

μ = 0.85 mm−1

T = 291 K

0.28 × 0.24 × 0.22 mm

Data collection

Rigaku Saturn 724 CCD diffractometer

Absorption correction: multi-scan (ABSCOR; Higashi, 1995 ▶) T min = 0.796, T max = 0.835

12764 measured reflections

5722 independent reflections

4078 reflections with I > 2σ(I)

R int = 0.022

Refinement

R[F 2 > 2σ(F 2)] = 0.057

wR(F 2) = 0.156

S = 0.97

5722 reflections

402 parameters

7 restraints

H atoms treated by a mixture of independent and constrained refinement

Δρmax = 0.42 e Å−3

Δρmin = −0.42 e Å−3

Data collection: CrystalClear (Rigaku, 2008 ▶); cell refinement: CrystalClear; data reduction: CrystalClear; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXS97 (Sheldrick, 2008 ▶); molecular graphics: DIAMOND (Brandenburg, 2006 ▶); software used to prepare material for publication: SHELXTL (Sheldrick, 2008 ▶).

Click here for additional data file.

Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536813010234/zl2544sup1.cif

Click here for additional data file.

Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813010234/zl2544Isup2.hkl

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[Fe2Ni(C19H12N3O)2(CN)6(C16H36N4)]·2.07H2O	F(000) = 1297.4
Mr = 1244.89	Dx = 1.384 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 3735 reflections
a = 9.4145 (13) Å	θ = 2.1–23.4°
b = 15.7309 (17) Å	µ = 0.85 mm−1
c = 20.590 (2) Å	T = 291 K
β = 101.781 (3)°	Block, black
V = 2985.1 (6) Å3	0.28 × 0.24 × 0.22 mm
Z = 2

Rigaku Saturn 724 CCD diffractometer	5722 independent reflections
Radiation source: fine-focus sealed tube	4078 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.022
φ and ω scans	θmax = 26.0°, θmin = 3.3°
Absorption correction: multi-scan (ABSCOR; Higashi, 1995)	h = −11→11
Tmin = 0.796, Tmax = 0.835	k = 0→19
12764 measured reflections	l = 0→25

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.057	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.156	H atoms treated by a mixture of independent and constrained refinement
S = 0.97	w = 1/[σ2(Fo2) + (0.095P)2] where P = (Fo2 + 2Fc2)/3
5722 reflections	(Δ/σ)max < 0.001
402 parameters	Δρmax = 0.42 e Å−3
7 restraints	Δρmin = −0.42 e Å−3

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. the restraints that were used for the refinement of the water H atoms are: DFIX 2.1 H2WA O1 DFIX 1.36 H1WA H1WB H2WA H2WB DFIX 0.82 O1W H1WA O1W H1WB O2W H2WA O2W H2WB

	x	y	z	Uiso*/Ueq	Occ. (<1)
C1	0.6080 (3)	0.3867 (2)	0.85132 (16)	0.0385 (8)
C2	0.4738 (3)	0.1784 (2)	0.92238 (15)	0.0381 (8)
C3	0.6764 (4)	0.2943 (3)	0.9657 (2)	0.0603 (12)
C4	0.4671 (4)	0.3845 (2)	1.00163 (18)	0.0439 (8)
H4	0.5580	0.3678	1.0250	0.053*
C5	0.3788 (4)	0.4394 (3)	1.03091 (17)	0.0475 (10)
H5	0.4135	0.4595	1.0737	0.057*
C6	0.2454 (4)	0.4634 (3)	0.99820 (18)	0.0535 (10)
H6	0.1895	0.4999	1.0182	0.064*
C7	0.1919 (4)	0.4330 (3)	0.93380 (19)	0.0507 (10)
C8	0.0562 (4)	0.4568 (3)	0.89958 (18)	0.0479 (9)
H8	−0.0011	0.4932	0.9188	0.057*
C9	0.0051 (4)	0.4247 (3)	0.83428 (19)	0.0556 (11)
H9	−0.0875	0.4387	0.8113	0.067*
C10	0.0903 (4)	0.3742 (3)	0.80565 (18)	0.0480 (9)
H10	0.0570	0.3549	0.7626	0.058*
C11	0.2293 (4)	0.3504 (3)	0.84038 (18)	0.0492 (9)
C12	0.2803 (3)	0.3806 (3)	0.90398 (17)	0.0431 (8)
C13	0.3175 (4)	0.2439 (3)	0.76782 (19)	0.0531 (10)
C14	0.4306 (4)	0.2005 (3)	0.76050 (17)	0.0470 (9)
C15	0.4349 (4)	0.1491 (3)	0.70543 (19)	0.0535 (10)
H15	0.3499	0.1343	0.6759	0.064*
C16	0.5658 (4)	0.1213 (3)	0.6960 (2)	0.0601 (11)
H16	0.5689	0.0894	0.6583	0.072*
C17	0.6919 (4)	0.1378 (3)	0.73891 (19)	0.0549 (10)
C18	0.8243 (4)	0.1087 (3)	0.7271 (2)	0.0565 (11)
H18	0.8272	0.0769	0.6893	0.068*
C19	0.9535 (4)	0.1276 (3)	0.7727 (2)	0.0536 (10)
H19	1.0420	0.1080	0.7652	0.064*
C20	0.9488 (4)	0.1744 (3)	0.8271 (2)	0.0539 (10)
H20	1.0342	0.1857	0.8576	0.065*
C21	0.8156 (4)	0.2063 (3)	0.8384 (2)	0.0534 (10)
H21	0.8136	0.2406	0.8750	0.064*
C22	0.6895 (4)	0.1863 (3)	0.79498 (18)	0.0462 (9)
C23	0.3339 (3)	−0.0867 (2)	0.86776 (16)	0.0393 (8)
C24	0.4859 (4)	−0.1054 (3)	0.85829 (17)	0.0447 (9)
H24A	0.5204	−0.1545	0.8855	0.054*
H24B	0.4782	−0.1227	0.8125	0.054*
C25	0.6028 (4)	−0.0390 (2)	0.87275 (16)	0.0393 (8)
H25	0.5618	0.0160	0.8561	0.047*
C26	0.7755 (4)	0.0258 (3)	0.96768 (17)	0.0453 (9)
H26A	0.7525	0.0793	0.9444	0.054*
H26B	0.8632	0.0035	0.9562	0.054*
C27	0.1984 (4)	−0.0414 (3)	0.95781 (16)	0.0449 (9)
H27A	0.1243	−0.0845	0.9453	0.054*
H27B	0.1649	0.0106	0.9342	0.054*
C28	0.2337 (4)	−0.1648 (3)	0.84162 (17)	0.0476 (9)
H28A	0.1373	−0.1542	0.8483	0.071*
H28B	0.2716	−0.2150	0.8655	0.071*
H28C	0.2312	−0.1728	0.7952	0.071*
C29	0.2665 (4)	−0.0076 (3)	0.82503 (19)	0.0472 (9)
H29A	0.2796	0.0425	0.8522	0.071*
H29B	0.1648	−0.0171	0.8085	0.071*
H29C	0.3142	−0.0003	0.7884	0.071*
C30	0.7320 (4)	−0.0618 (3)	0.83749 (18)	0.0462 (9)
H30A	0.7018	−0.1060	0.8054	0.069*
H30B	0.8137	−0.0811	0.8700	0.069*
H30C	0.7589	−0.0123	0.8156	0.069*
Ni1	0.5000	0.0000	1.0000	0.0353 (2)
Fe1	0.52931 (5)	0.28363 (4)	0.88333 (2)	0.04223 (18)
N1	0.6534 (3)	0.4476 (2)	0.83299 (14)	0.0454 (7)
N2	0.7764 (3)	0.2701 (3)	1.00090 (15)	0.0622 (10)
N3	0.4567 (3)	0.1146 (2)	0.94597 (14)	0.0420 (7)
N4	0.4158 (3)	0.3561 (2)	0.93779 (15)	0.0461 (8)
N5	0.3195 (3)	0.2951 (2)	0.81931 (14)	0.0445 (7)
N6	0.5568 (3)	0.2176 (2)	0.80568 (15)	0.0478 (8)
N7	0.3381 (3)	−0.0703 (2)	0.93949 (14)	0.0412 (7)
H7	0.3509	−0.1232	0.9576	0.049*
N8	0.6599 (3)	−0.0325 (2)	0.94730 (12)	0.0363 (6)
H8A	0.6936	−0.0848	0.9616	0.044*
O1	0.2120 (3)	0.2298 (2)	0.72506 (14)	0.0600 (8)
O1W	0.2133 (5)	0.2873 (4)	0.5217 (3)	0.066 (2)	0.528 (10)
H1WA	0.142 (7)	0.280 (7)	0.540 (4)	0.100*	0.528 (10)
H1WB	0.186 (9)	0.273 (8)	0.4823 (19)	0.100*	0.528 (10)
O2W	0.0492 (5)	0.2088 (4)	0.5914 (2)	0.059 (2)	0.506 (9)
H2WA	0.089 (9)	0.196 (3)	0.6296 (15)	0.088*	0.506 (9)
H2WB	0.051 (11)	0.177 (4)	0.562 (2)	0.088*	0.506 (9)

	U11	U22	U33	U12	U13	U23
C1	0.0440 (16)	0.032 (2)	0.0422 (18)	0.0046 (15)	0.0141 (14)	0.0035 (16)
C2	0.0486 (17)	0.040 (2)	0.0293 (16)	0.0066 (15)	0.0166 (13)	0.0102 (15)
C3	0.0380 (17)	0.065 (3)	0.071 (3)	−0.0173 (17)	−0.0054 (17)	0.033 (2)
C4	0.0407 (15)	0.039 (2)	0.053 (2)	0.0031 (16)	0.0106 (14)	0.0069 (17)
C5	0.0520 (18)	0.053 (3)	0.0423 (18)	−0.0232 (17)	0.0210 (15)	−0.0186 (18)
C6	0.064 (2)	0.053 (3)	0.050 (2)	0.013 (2)	0.0258 (18)	0.015 (2)
C7	0.0521 (19)	0.041 (2)	0.063 (2)	0.0119 (17)	0.0223 (17)	0.0165 (19)
C8	0.0507 (18)	0.049 (3)	0.049 (2)	0.0148 (17)	0.0218 (16)	0.0165 (19)
C9	0.0426 (17)	0.070 (3)	0.057 (2)	0.0203 (18)	0.0152 (16)	0.028 (2)
C10	0.0452 (17)	0.051 (3)	0.0476 (19)	−0.0102 (17)	0.0088 (15)	−0.0018 (18)
C11	0.0509 (18)	0.047 (3)	0.053 (2)	0.0161 (17)	0.0185 (16)	0.0152 (19)
C12	0.0443 (17)	0.043 (2)	0.0457 (19)	0.0084 (16)	0.0187 (15)	0.0112 (17)
C13	0.066 (2)	0.047 (3)	0.043 (2)	−0.0011 (19)	0.0043 (18)	−0.0028 (19)
C14	0.0513 (18)	0.052 (3)	0.0377 (18)	−0.0157 (17)	0.0102 (14)	−0.0001 (17)
C15	0.0537 (19)	0.054 (3)	0.054 (2)	−0.0229 (18)	0.0128 (16)	−0.017 (2)
C16	0.054 (2)	0.060 (3)	0.069 (3)	−0.002 (2)	0.0193 (19)	−0.004 (2)
C17	0.058 (2)	0.057 (3)	0.056 (2)	−0.0156 (19)	0.0268 (18)	−0.015 (2)
C18	0.062 (2)	0.059 (3)	0.056 (2)	−0.009 (2)	0.0284 (19)	−0.018 (2)
C19	0.0438 (18)	0.055 (3)	0.065 (2)	0.0123 (17)	0.0201 (17)	0.018 (2)
C20	0.0451 (17)	0.055 (3)	0.065 (2)	0.0106 (17)	0.0180 (17)	0.023 (2)
C21	0.0485 (18)	0.046 (3)	0.072 (3)	0.0142 (17)	0.0268 (18)	0.021 (2)
C22	0.0518 (19)	0.043 (2)	0.050 (2)	−0.0107 (17)	0.0247 (16)	−0.0084 (18)
C23	0.0411 (15)	0.035 (2)	0.0445 (18)	0.0026 (14)	0.0162 (14)	0.0054 (16)
C24	0.0525 (18)	0.044 (2)	0.0407 (18)	0.0126 (17)	0.0179 (15)	−0.0069 (17)
C25	0.0500 (17)	0.036 (2)	0.0348 (16)	0.0095 (15)	0.0165 (14)	0.0013 (16)
C26	0.0458 (17)	0.044 (2)	0.050 (2)	0.0035 (16)	0.0183 (15)	−0.0004 (18)
C27	0.0433 (16)	0.050 (3)	0.0411 (18)	0.0061 (16)	0.0088 (14)	0.0074 (18)
C28	0.0572 (19)	0.040 (2)	0.0416 (19)	−0.0095 (17)	0.0016 (15)	−0.0048 (17)
C29	0.0477 (19)	0.045 (3)	0.046 (2)	−0.0012 (15)	0.0013 (16)	0.0163 (17)
C30	0.0503 (17)	0.043 (2)	0.049 (2)	0.0150 (16)	0.0192 (15)	0.0126 (18)
Ni1	0.0407 (3)	0.0359 (4)	0.0322 (3)	0.0059 (2)	0.0141 (3)	0.0083 (3)
Fe1	0.0481 (3)	0.0385 (4)	0.0415 (3)	−0.0006 (2)	0.0123 (2)	0.0128 (2)
N1	0.0450 (14)	0.053 (2)	0.0410 (15)	−0.0037 (14)	0.0156 (12)	0.0039 (15)
N2	0.0565 (18)	0.075 (3)	0.0459 (18)	−0.0148 (18)	−0.0120 (15)	0.0167 (18)
N3	0.0428 (14)	0.037 (2)	0.0476 (17)	0.0098 (13)	0.0120 (12)	0.0068 (15)
N4	0.0432 (13)	0.049 (2)	0.0480 (17)	−0.0025 (14)	0.0137 (13)	0.0156 (16)
N5	0.0503 (15)	0.043 (2)	0.0461 (16)	−0.0048 (14)	0.0225 (13)	0.0056 (14)
N6	0.0488 (15)	0.045 (2)	0.0516 (17)	−0.0068 (14)	0.0159 (13)	0.0114 (15)
N7	0.0451 (14)	0.0350 (18)	0.0457 (16)	0.0004 (12)	0.0143 (12)	0.0065 (14)
N8	0.0425 (13)	0.0369 (18)	0.0326 (13)	0.0078 (12)	0.0145 (11)	0.0066 (13)
O1	0.0569 (15)	0.062 (2)	0.0602 (16)	−0.0231 (14)	0.0095 (13)	0.0007 (15)
O1W	0.052 (3)	0.072 (5)	0.074 (4)	−0.013 (3)	0.009 (3)	−0.005 (3)
O2W	0.054 (3)	0.073 (5)	0.039 (3)	−0.021 (3)	−0.017 (2)	−0.009 (3)

C1—N1	1.144 (5)	C22—N6	1.401 (5)
C1—Fe1	1.952 (4)	C23—N7	1.492 (4)
C2—N3	1.140 (5)	C23—C24	1.513 (4)
C2—Fe1	1.958 (4)	C23—C28	1.576 (5)
C3—N2	1.131 (5)	C23—C29	1.579 (5)
C3—Fe1	1.965 (4)	C24—C25	1.503 (5)
C4—N4	1.378 (5)	C24—H24A	0.9700
C4—C5	1.416 (5)	C24—H24B	0.9700
C4—H4	0.9300	C25—N8	1.523 (4)
C5—C6	1.353 (5)	C25—C30	1.580 (4)
C5—H5	0.9300	C25—H25	0.9800
C6—C7	1.403 (6)	C26—N8	1.420 (5)
C6—H6	0.9300	C26—C27i	1.523 (5)
C7—C8	1.378 (5)	C26—H26A	0.9700
C7—C12	1.399 (5)	C26—H26B	0.9700
C8—C9	1.424 (6)	C27—N7	1.511 (4)
C8—H8	0.9300	C27—C26i	1.523 (5)
C9—C10	1.347 (6)	C27—H27A	0.9700
C9—H9	0.9300	C27—H27B	0.9700
C10—C11	1.408 (5)	C28—H28A	0.9600
C10—H10	0.9300	C28—H28B	0.9600
C11—N5	1.349 (5)	C28—H28C	0.9600
C11—C12	1.384 (5)	C29—H29A	0.9600
C12—N4	1.378 (4)	C29—H29B	0.9600
C13—O1	1.206 (5)	C29—H29C	0.9600
C13—C14	1.300 (6)	C30—H30A	0.9600
C13—N5	1.328 (5)	C30—H30B	0.9600
C14—N6	1.378 (5)	C30—H30C	0.9600
C14—C15	1.400 (5)	Ni1—N7i	2.079 (3)
C15—C16	1.359 (5)	Ni1—N7	2.079 (3)
C15—H15	0.9300	Ni1—N8i	2.091 (2)
C16—C17	1.352 (6)	Ni1—N8	2.091 (2)
C16—H16	0.9300	Ni1—N3i	2.114 (3)
C17—C22	1.388 (5)	Ni1—N3	2.114 (3)
C17—C18	1.395 (5)	Fe1—N6	1.967 (3)
C18—C19	1.409 (5)	Fe1—N4	2.047 (3)
C18—H18	0.9300	Fe1—N5	2.147 (3)
C19—C20	1.349 (6)	N7—H7	0.9100
C19—H19	0.9300	N8—H8A	0.9100
C20—C21	1.414 (5)	O1W—H1WA	0.85 (2)
C20—H20	0.9300	O1W—H1WB	0.83 (2)
C21—C22	1.369 (5)	O2W—H2WA	0.82 (2)
C21—H21	0.9300	O2W—H2WB	0.79 (2)
N1—C1—Fe1	179.3 (3)	N8—C26—H26B	109.5
N3—C2—Fe1	172.6 (3)	C27i—C26—H26B	109.5
N2—C3—Fe1	150.8 (5)	H26A—C26—H26B	108.0
N4—C4—C5	118.8 (3)	N7—C27—C26i	109.3 (3)
N4—C4—H4	120.6	N7—C27—H27A	109.8
C5—C4—H4	120.6	C26i—C27—H27A	109.8
C6—C5—C4	121.6 (3)	N7—C27—H27B	109.8
C6—C5—H5	119.2	C26i—C27—H27B	109.8
C4—C5—H5	119.2	H27A—C27—H27B	108.3
C5—C6—C7	119.5 (4)	C23—C28—H28A	109.5
C5—C6—H6	120.2	C23—C28—H28B	109.5
C7—C6—H6	120.2	H28A—C28—H28B	109.5
C8—C7—C12	120.5 (4)	C23—C28—H28C	109.5
C8—C7—C6	120.4 (4)	H28A—C28—H28C	109.5
C12—C7—C6	119.0 (3)	H28B—C28—H28C	109.5
C7—C8—C9	119.1 (4)	C23—C29—H29A	109.5
C7—C8—H8	120.5	C23—C29—H29B	109.5
C9—C8—H8	120.5	H29A—C29—H29B	109.5
C10—C9—C8	120.3 (3)	C23—C29—H29C	109.5
C10—C9—H9	119.8	H29A—C29—H29C	109.5
C8—C9—H9	119.8	H29B—C29—H29C	109.5
C9—C10—C11	120.6 (4)	C25—C30—H30A	109.5
C9—C10—H10	119.7	C25—C30—H30B	109.5
C11—C10—H10	119.7	H30A—C30—H30B	109.5
N5—C11—C12	114.0 (3)	C25—C30—H30C	109.5
N5—C11—C10	126.1 (4)	H30A—C30—H30C	109.5
C12—C11—C10	119.8 (3)	H30B—C30—H30C	109.5
N4—C12—C11	119.3 (3)	N7i—Ni1—N7	180.0
N4—C12—C7	121.0 (3)	N7i—Ni1—N8i	94.38 (11)
C11—C12—C7	119.7 (3)	N7—Ni1—N8i	85.62 (11)
O1—C13—C14	113.0 (4)	N7i—Ni1—N8	85.62 (11)
O1—C13—N5	124.7 (4)	N7—Ni1—N8	94.38 (11)
C14—C13—N5	122.2 (4)	N8i—Ni1—N8	179.998 (1)
C13—C14—N6	115.6 (4)	N7i—Ni1—N3i	95.69 (12)
C13—C14—C15	123.8 (4)	N7—Ni1—N3i	84.31 (12)
N6—C14—C15	119.8 (3)	N8i—Ni1—N3i	90.98 (11)
C16—C15—C14	118.6 (4)	N8—Ni1—N3i	89.02 (11)
C16—C15—H15	120.7	N7i—Ni1—N3	84.31 (12)
C14—C15—H15	120.7	N7—Ni1—N3	95.69 (12)
C17—C16—C15	123.1 (4)	N8i—Ni1—N3	89.02 (11)
C17—C16—H16	118.4	N8—Ni1—N3	90.98 (11)
C15—C16—H16	118.4	N3i—Ni1—N3	179.999 (1)
C16—C17—C22	119.2 (4)	C1—Fe1—C2	173.01 (14)
C16—C17—C18	121.3 (4)	C1—Fe1—C3	88.36 (15)
C22—C17—C18	119.5 (4)	C2—Fe1—C3	85.30 (15)
C17—C18—C19	119.7 (4)	C1—Fe1—N6	92.41 (13)
C17—C18—H18	120.2	C2—Fe1—N6	88.74 (13)
C19—C18—H18	120.2	C3—Fe1—N6	124.04 (17)
C20—C19—C18	119.9 (3)	C1—Fe1—N4	89.92 (13)
C20—C19—H19	120.0	C2—Fe1—N4	91.90 (13)
C18—C19—H19	120.0	C3—Fe1—N4	80.47 (16)
C19—C20—C21	120.8 (4)	N6—Fe1—N4	155.42 (12)
C19—C20—H20	119.6	C1—Fe1—N5	95.05 (13)
C21—C20—H20	119.6	C2—Fe1—N5	91.93 (13)
C22—C21—C20	119.4 (4)	C3—Fe1—N5	157.02 (16)
C22—C21—H21	120.3	N6—Fe1—N5	78.60 (12)
C20—C21—H21	120.3	N4—Fe1—N5	76.82 (12)
C21—C22—C17	120.7 (3)	C2—N3—Ni1	161.0 (3)
C21—C22—N6	119.9 (3)	C12—N4—C4	119.9 (3)
C17—C22—N6	119.4 (3)	C12—N4—Fe1	114.3 (2)
N7—C23—C24	109.1 (3)	C4—N4—Fe1	125.6 (2)
N7—C23—C28	111.5 (3)	C13—N5—C11	137.8 (3)
C24—C23—C28	108.6 (3)	C13—N5—Fe1	107.5 (2)
N7—C23—C29	110.0 (3)	C11—N5—Fe1	114.7 (2)
C24—C23—C29	111.4 (3)	C14—N6—C22	119.9 (3)
C28—C23—C29	106.2 (3)	C14—N6—Fe1	114.4 (2)
C25—C24—C23	120.8 (3)	C22—N6—Fe1	125.6 (2)
C25—C24—H24A	107.1	C23—N7—C27	116.8 (2)
C23—C24—H24A	107.1	C23—N7—Ni1	123.6 (2)
C25—C24—H24B	107.1	C27—N7—Ni1	105.0 (2)
C23—C24—H24B	107.1	C23—N7—H7	102.8
H24A—C24—H24B	106.8	C27—N7—H7	102.8
C24—C25—N8	109.9 (3)	Ni1—N7—H7	102.8
C24—C25—C30	110.6 (3)	C26—N8—C25	115.7 (3)
N8—C25—C30	109.4 (3)	C26—N8—Ni1	106.2 (2)
C24—C25—H25	109.0	C25—N8—Ni1	113.33 (18)
N8—C25—H25	109.0	C26—N8—H8A	107.1
C30—C25—H25	109.0	C25—N8—H8A	107.1
N8—C26—C27i	110.9 (3)	Ni1—N8—H8A	107.1
N8—C26—H26A	109.5	H1WA—O1W—H1WB	106 (3)
C27i—C26—H26A	109.5	H2WA—O2W—H2WB	120 (4)
N4—C4—C5—C6	1.1 (6)	N5—Fe1—N4—C4	176.8 (3)
C4—C5—C6—C7	0.4 (6)	O1—C13—N5—C11	−7.4 (8)
C5—C6—C7—C8	−179.9 (4)	C14—C13—N5—C11	175.9 (4)
C5—C6—C7—C12	−2.2 (6)	O1—C13—N5—Fe1	173.8 (4)
C12—C7—C8—C9	2.3 (6)	C14—C13—N5—Fe1	−3.0 (5)
C6—C7—C8—C9	180.0 (4)	C12—C11—N5—C13	172.3 (4)
C7—C8—C9—C10	−2.2 (6)	C10—C11—N5—C13	−3.6 (7)
C8—C9—C10—C11	1.7 (6)	C12—C11—N5—Fe1	−8.9 (4)
C9—C10—C11—N5	174.3 (4)	C10—C11—N5—Fe1	175.2 (3)
C9—C10—C11—C12	−1.4 (6)	C1—Fe1—N5—C13	99.2 (3)
N5—C11—C12—N4	3.1 (5)	C2—Fe1—N5—C13	−80.6 (3)
C10—C11—C12—N4	179.2 (3)	C3—Fe1—N5—C13	−163.1 (4)
N5—C11—C12—C7	−174.7 (4)	N6—Fe1—N5—C13	7.8 (3)
C10—C11—C12—C7	1.5 (6)	N4—Fe1—N5—C13	−172.1 (3)
C8—C7—C12—N4	−179.7 (3)	C1—Fe1—N5—C11	−80.0 (3)
C6—C7—C12—N4	2.6 (6)	C2—Fe1—N5—C11	100.3 (3)
C8—C7—C12—C11	−2.0 (6)	C3—Fe1—N5—C11	17.8 (5)
C6—C7—C12—C11	−179.7 (4)	N6—Fe1—N5—C11	−171.4 (3)
O1—C13—C14—N6	176.3 (3)	N4—Fe1—N5—C11	8.8 (3)
N5—C13—C14—N6	−6.6 (6)	C13—C14—N6—C22	−168.2 (4)
O1—C13—C14—C15	6.0 (6)	C15—C14—N6—C22	2.5 (5)
N5—C13—C14—C15	−176.9 (4)	C13—C14—N6—Fe1	13.6 (5)
C13—C14—C15—C16	166.2 (4)	C15—C14—N6—Fe1	−175.7 (3)
N6—C14—C15—C16	−3.7 (6)	C21—C22—N6—C14	177.3 (4)
C14—C15—C16—C17	3.0 (7)	C17—C22—N6—C14	−0.4 (6)
C15—C16—C17—C22	−0.9 (7)	C21—C22—N6—Fe1	−4.8 (5)
C15—C16—C17—C18	−179.4 (4)	C17—C22—N6—Fe1	177.6 (3)
C16—C17—C18—C19	179.6 (4)	C1—Fe1—N6—C14	−106.1 (3)
C22—C17—C18—C19	1.1 (7)	C2—Fe1—N6—C14	80.8 (3)
C17—C18—C19—C20	−0.6 (7)	C3—Fe1—N6—C14	164.3 (3)
C18—C19—C20—C21	−1.4 (6)	N4—Fe1—N6—C14	−11.0 (5)
C19—C20—C21—C22	2.9 (6)	N5—Fe1—N6—C14	−11.4 (3)
C20—C21—C22—C17	−2.4 (6)	C1—Fe1—N6—C22	75.9 (3)
C20—C21—C22—N6	−180.0 (3)	C2—Fe1—N6—C22	−97.2 (3)
C16—C17—C22—C21	−178.1 (4)	C3—Fe1—N6—C22	−13.7 (4)
C18—C17—C22—C21	0.5 (6)	N4—Fe1—N6—C22	171.0 (3)
C16—C17—C22—N6	−0.5 (6)	N5—Fe1—N6—C22	170.6 (3)
C18—C17—C22—N6	178.1 (4)	C24—C23—N7—C27	173.9 (3)
N7—C23—C24—C25	−64.1 (4)	C28—C23—N7—C27	−66.2 (4)
C28—C23—C24—C25	174.2 (3)	C29—C23—N7—C27	51.4 (4)
C29—C23—C24—C25	57.5 (4)	C24—C23—N7—Ni1	40.7 (4)
C23—C24—C25—N8	78.0 (4)	C28—C23—N7—Ni1	160.7 (2)
C23—C24—C25—C30	−161.2 (3)	C29—C23—N7—Ni1	−81.7 (3)
N2—C3—Fe1—C1	−113.9 (7)	C26i—C27—N7—C23	−178.6 (3)
N2—C3—Fe1—C2	63.2 (7)	C26i—C27—N7—Ni1	−37.6 (3)
N2—C3—Fe1—N6	−22.1 (7)	N8i—Ni1—N7—C23	150.3 (3)
N2—C3—Fe1—N4	156.0 (7)	N8—Ni1—N7—C23	−29.7 (3)
N2—C3—Fe1—N5	147.1 (6)	N3i—Ni1—N7—C23	−118.2 (3)
N7i—Ni1—N3—C2	33.8 (8)	N3—Ni1—N7—C23	61.8 (3)
N7—Ni1—N3—C2	−146.2 (8)	N8i—Ni1—N7—C27	12.8 (2)
N8i—Ni1—N3—C2	128.3 (9)	N8—Ni1—N7—C27	−167.2 (2)
N8—Ni1—N3—C2	−51.7 (9)	N3i—Ni1—N7—C27	104.2 (2)
C11—C12—N4—C4	−178.9 (3)	N3—Ni1—N7—C27	−75.8 (2)
C7—C12—N4—C4	−1.1 (5)	C27i—C26—N8—C25	167.7 (3)
C11—C12—N4—Fe1	4.6 (4)	C27i—C26—N8—Ni1	41.1 (3)
C7—C12—N4—Fe1	−177.7 (3)	C24—C25—N8—C26	177.5 (3)
C5—C4—N4—C12	−0.7 (5)	C30—C25—N8—C26	55.9 (4)
C5—C4—N4—Fe1	175.4 (3)	C24—C25—N8—Ni1	−59.6 (3)
C1—Fe1—N4—C12	88.3 (3)	C30—C25—N8—Ni1	178.8 (2)
C2—Fe1—N4—C12	−98.4 (3)	N7i—Ni1—N8—C26	−15.4 (2)
C3—Fe1—N4—C12	176.7 (3)	N7—Ni1—N8—C26	164.6 (2)
N6—Fe1—N4—C12	−7.3 (5)	N3i—Ni1—N8—C26	−111.1 (2)
N5—Fe1—N4—C12	−6.9 (2)	N3—Ni1—N8—C26	68.9 (2)
C1—Fe1—N4—C4	−88.0 (3)	N7i—Ni1—N8—C25	−143.4 (2)
C2—Fe1—N4—C4	85.3 (3)	N7—Ni1—N8—C25	36.6 (2)
C3—Fe1—N4—C4	0.4 (3)	N3i—Ni1—N8—C25	120.8 (2)
N6—Fe1—N4—C4	176.4 (3)	N3—Ni1—N8—C25	−59.2 (2)

D—H···A	D—H	H···A	D···A	D—H···A
O2W—H2WA···O1	0.82 (2)	2.14 (2)	2.882 (5)	151 (5)
O1W—H1WA···O2W	0.85 (2)	1.87 (7)	2.623 (8)	147 (11)
N8—H8A···O1Wii	0.91	2.19	3.091 (7)	169

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O2W—H2WA⋯O1	0.82 (2)	2.14 (2)	2.882 (5)	151 (5)
O1W—H1WA⋯O2W	0.85 (2)	1.87 (7)	2.623 (8)	147 (11)
N8—H8A⋯O1W i	0.91	2.19	3.091 (7)	169

Symmetry code: (i) .