Literature DB >> 23722554

The first general route for efficient synthesis of 18O labelled alcohols using the HOF·CH3CN complex.

Julia Gatenyo1, Inna Vints, Shlomo Rozen.   

Abstract

A mild and very efficient method for converting boronic acids to alcohols has been developed using the acetonitrile complex of hypofluorous acid HOF·CH3CN. Employing (18)O-labeled water results in alcohols containing a heavy oxygen isotope. The reactions were performed at room temperature, within a few minutes and in excellent yields.

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Year:  2013        PMID: 23722554     DOI: 10.1039/c3cc42337a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Transition-Metal-Free ipso-Functionalization of Arylboronic Acids and Derivatives.

Authors:  Chen Zhu; John R Falck
Journal:  Adv Synth Catal       Date:  2014-08-11       Impact factor: 5.837

2.  Aerobic photooxidative hydroxylation of boronic acids catalyzed by anthraquinone-containing polymeric photosensitizer.

Authors:  Yang Chen; Jianhua Hu; Aishun Ding
Journal:  RSC Adv       Date:  2020-02-24       Impact factor: 4.036

  2 in total

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