Literature DB >> 23715008

Enantioselective self-assembly of antiferromagnetic hexacopper(II) wheels with chiral amino acid oxamates.

Thais Grancha1, Jesús Ferrando-Soria, Joan Cano, Francesc Lloret, Miguel Julve, Giovanni De Munno, Donatella Armentano, Emilio Pardo.   

Abstract

The Cu(2+)-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.

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Year:  2013        PMID: 23715008     DOI: 10.1039/c3cc42776e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Homochiral self-assembly of biocoordination polymers: anion-triggered helicity and absolute configuration inversion.

Authors:  Nadia Marino; Donatella Armentano; Emilio Pardo; Julia Vallejo; Francesco Neve; Leonardo Di Donna; Giovanni De Munno
Journal:  Chem Sci       Date:  2015-04-30       Impact factor: 9.825

  1 in total

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