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Literature DB >> 23713867

Plutonium(IV) cluster with a hexanuclear [Pu6(OH)4O4]12+ core.

Abstract

A mixed hydroxo/oxo plutonium(IV) carboxylate resulting from the hydrolysis and condensation of Pu(IV) in an acidic aqueous solution has been isolated. The structure of Li6[Pu6(OH)4O4(H2O)6(HGly)12]Cl18·10.5H2O (1) consists of a cationic [Pu6(OH)4O4](12+) core that is decorated by glycine ligands. The synthesis, structure, and characterization of the hexanuclear unit, which represents the first example of a Pu(IV) polynuclear complex containing both hydroxo- and oxo-bridging ligands, are described herein.

Entities: Chemical

Year: 2013 PMID： 23713867 DOI： 10.1021/ic4007185

Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165

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Cited

4 in total

1. Size and structure of hexanuclear plutonium oxo-hydroxo clusters in aqueous solution from synchrotron analysis.

Authors: Thomas Dumas; Matthieu Virot; Denis Menut; Christelle Tamain; Cyril Micheau; Sandrine Dourdain; Olivier Diat
Journal: J Synchrotron Radiat Date: 2022-01-01 Impact factor: 2.616

2. To form or not to form: PuO₂ nanoparticles at acidic pH.

Authors: Evgeny Gerber; Anna Yu Romanchuk; Stephan Weiss; Anastasiia Kuzenkova; Myrtille O J Y Hunault; Stephen Bauters; Alexander Egorov; Sergei M Butorin; Stepan N Kalmykov; Kristina O Kvashnina
Journal: Environ Sci Nano Date: 2022-03-11

3. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)₂ followed by the formation of molecular poly-oxo cluster {U₁₄} containing hemimellitate uranium(iv).

Authors: Maxime Dufaye; Nicolas P Martin; Sylvain Duval; Christophe Volkringer; Atsushi Ikeda-Ohno; Thierry Loiseau
Journal: RSC Adv Date: 2019-07-23 Impact factor: 4.036

4. Formation of a new type of uranium(iv) poly-oxo cluster {U₃₈} based on a controlled release of water via esterification reaction.

Authors: Nicolas P Martin; Christophe Volkringer; Natacha Henry; Xavier Trivelli; Grégory Stoclet; Atsushi Ikeda-Ohno; Thierry Loiseau
Journal: Chem Sci Date: 2018-05-09 Impact factor: 9.825

4 in total

Plutonium(IV) cluster with a hexanuclear [Pu6(OH)4O4]12+ core.

1. Size and structure of hexanuclear plutonium oxo-hydroxo clusters in aqueous solution from synchrotron analysis.

2. To form or not to form: PuO2 nanoparticles at acidic pH.

3. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)2 followed by the formation of molecular poly-oxo cluster {U14} containing hemimellitate uranium(iv).

4. Formation of a new type of uranium(iv) poly-oxo cluster {U38} based on a controlled release of water via esterification reaction.

2. To form or not to form: PuO₂ nanoparticles at acidic pH.

3. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)₂ followed by the formation of molecular poly-oxo cluster {U₁₄} containing hemimellitate uranium(iv).

4. Formation of a new type of uranium(iv) poly-oxo cluster {U₃₈} based on a controlled release of water via esterification reaction.