Literature DB >> 23713519

Copolymerization of epoxides with carbon dioxide catalyzed by iron-corrole complexes: synthesis of a crystalline copolymer.

Koji Nakano1, Kazuki Kobayashi, Takahiro Ohkawara, Hideyuki Imoto, Kyoko Nozaki.   

Abstract

Iron-corrole complexes were found to copolymerize epoxides with CO2. The first iron-catalyzed propylene oxide/CO2 copolymerization has been accomplished. Moreover, the glycidyl phenyl ether (GPE)/CO2 copolymerization with this catalyst provided a crystalline material as a result of the isotactic poly(GPE) moiety.

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Year:  2013        PMID： 23713519     DOI： 10.1021/ja4028633

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Crystalline CO2-based polycarbonates prepared from racemic catalyst through intramolecularly interlocked assembly.

Authors:  Ye Liu; Wei-Min Ren; Wei-Ping Zhang; Rong-Rong Zhao; Xiao-Bing Lu
Journal:  Nat Commun       Date:  2015-10-15       Impact factor: 14.919

2.  CO2 Fixation with Epoxides under Mild Conditions with a Cooperative Metal Corrole/Quaternary Ammonium Salt Catalyst System.

Authors:  Maximilian Tiffner; Sabrina Gonglach; Michael Haas; Wolfgang Schöfberger; Mario Waser
Journal:  Chem Asian J       Date:  2017-04-20

3.  Direct Copolymerization of CO2 and Diols.

Authors:  Masazumi Tamura; Kazuki Ito; Masayoshi Honda; Yoshinao Nakagawa; Hiroshi Sugimoto; Keiichi Tomishige
Journal:  Sci Rep       Date:  2016-04-14       Impact factor: 4.379

4.  Heterodinuclear Mg(II)M(II) (M=Cr, Mn, Fe, Co, Ni, Cu and Zn) Complexes for the Ring Opening Copolymerization of Carbon Dioxide/Epoxide and Anhydride/Epoxide.

Authors:  Natalia V Reis; Arron C Deacy; Gloria Rosetto; Christopher B Durr; Charlotte K Williams
Journal:  Chemistry       Date:  2022-02-17       Impact factor: 5.020
  4 in total

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