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Literature DB >> 23713474

A mild chemoselective Ru-catalyzed reduction of alkynes, ketones, and nitro compounds.

Tobias Schabel¹, Christian Belger, Bernd Plietker.

Abstract

The chemoselective reduction of alkyne, ketones, or nitro groups using (Ph3P)3RuCl2 as an inexpensive catalyst and Zn/water as a stoichiometric reductant is reported. Depending on the nature of the additive and the temperature, good chemoselectivities were observed allowing, e.g., for the selective reduction of a nitro group in the presence of a ketone or an alkyne.

Entities: Chemical

Year: 2013 PMID： 23713474 DOI： 10.1021/ol401185t

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

5 in total

1. Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

Authors: Wei Feng; Tingting Huang; Liqian Gao; Xianfeng Yang; Wenbin Deng; Rui Zhou; Hongjun Liu
Journal: RSC Adv Date: 2018-02-07 Impact factor: 3.361

5. Unprotected and interconnected Ru⁰ nano-chain networks: advantages of unprotected surfaces in catalysis and electrocatalysis.

Authors: S Anantharaj; M Jayachandran; Subrata Kundu
Journal: Chem Sci Date: 2016-01-20 Impact factor: 9.825

5 in total

A mild chemoselective Ru-catalyzed reduction of alkynes, ketones, and nitro compounds.

1. Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

2. Ruthenium-Catalyzed E-Selective Alkyne Semihydrogenation with Alcohols as Hydrogen Donors.

3. Nickel-Catalyzed Stereodivergent Synthesis of E- and Z-Alkenes by Hydrogenation of Alkynes.

4. Mild, Selective Ru-Catalyzed Deuteration Using D₂ O as a Deuterium Source.

5. Unprotected and interconnected Ru⁰ nano-chain networks: advantages of unprotected surfaces in catalysis and electrocatalysis.

A mild chemoselective Ru-catalyzed reduction of alkynes, ketones, and nitro compounds.

1. Textile-supported silver nanoparticles as a highly efficient and recyclable heterogeneous catalyst for nitroaromatic reduction at room temperature.

2. Ruthenium-Catalyzed E-Selective Alkyne Semihydrogenation with Alcohols as Hydrogen Donors.

3. Nickel-Catalyzed Stereodivergent Synthesis of E- and Z-Alkenes by Hydrogenation of Alkynes.

4. Mild, Selective Ru-Catalyzed Deuteration Using D2 O as a Deuterium Source.

5. Unprotected and interconnected Ru0 nano-chain networks: advantages of unprotected surfaces in catalysis and electrocatalysis.

4. Mild, Selective Ru-Catalyzed Deuteration Using D₂ O as a Deuterium Source.

5. Unprotected and interconnected Ru⁰ nano-chain networks: advantages of unprotected surfaces in catalysis and electrocatalysis.